(S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl

Base Information

• Chemical Name: (S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl
• CAS No.: 1613753-09-5
• Molecular Formula: C₃₀H₃₂BrCrO₂P
• Molecular Weight: 587.457

Synonyms:(S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl

Chemical Property of (S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl

There total 1 articles about (S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

bis(3,5-dimethylphenyl)methallylphosphine (1613753-05-1) + (η6-1-bromo-2-vinylbenzene)chromium tricarbonyl (1379611-07-0,1613760-81-8,1613760-86-3) → (S)-(+)-(η6-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl (1613753-09-5)

Guidance literature:

In benzene; at 20 ℃; for 7h; enantioselective reaction; Irradiation; Inert atmosphere;

DOI:10.1021/ja503060e

Reference yield: 93.0%

(S)-(+)-(η6-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl (1613753-09-5) → (S)-(-)-[η6-1-bromo-2-(3-bis(3,5-dimethylphenyl)phosphino-2-methylpropenyl)benzene-P]chromium(0) dicarbonyl (1613753-14-2)

Guidance literature:

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; at 50 ℃; for 18h; enantioselective reaction; Inert atmosphere;

DOI:10.1021/ja503060e

upstream raw materials:

bis(3,5-dimethylphenyl)methallylphosphine

(η⁶-1-bromo-2-vinylbenzene)chromium tricarbonyl

Downstream raw materials:

(S)-(-)-[η⁶-1-bromo-2-(3-bis(3,5-dimethylphenyl)phosphino-2-methylpropenyl)benzene-P]chromium(0) dicarbonyl

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1613753-09-5 (S)-(+)-(η⁶-1-bromo-2-vinylbenzene)[diisopropyl(2-methylallyl)phosphine]chromium(0) dicarbonyl

Send

Send

Metric Ton KG G Pound L ML

Send

Send