5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester

Base Information

• Chemical Name: 5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester
• CAS No.: 1196459-36-5
• Molecular Formula: C₆₁H₈₈O₆S₄
• Molecular Weight: 1045.63
• Mol file: 1196459-36-5.mol

Synonyms:5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester

Chemical Property of 5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester

There total 1 articles about 5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

5''-bromo-[2,2';5',2'']-terthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester (1196459-35-4) + (5-formylthiophen-2-yl)boronic acid → 5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester (1196459-36-5)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; at 80 ℃; for 21h; Inert atmosphere;

DOI:10.1002/chem.200901336

Reference yield: 85.0%

5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester (1196459-36-5) → C61H90O6S4 (1263294-52-5)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; for 1h; Inert atmosphere;

DOI:10.1039/c0cc02225j

Reference yield: 64.0%

BARBITURIC ACID (67-52-7,944357-77-1) + 5'''-formyl-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester (1196459-36-5) → 5'''-(2,4,6-trioxo-tetrahydro-pyrimidin-5-ylidenemethyl)-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester (1196459-31-0)

Guidance literature:

In ethanol; for 48h; Inert atmosphere; Reflux;

DOI:10.1002/chem.200901336

upstream raw materials:

5''-bromo-[2,2';5',2'']-terthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester

Downstream raw materials:

5'''-(2,4,6-trioxo-tetrahydro-pyrimidin-5-ylidenemethyl)-[2,2';5',2'';5'',2''']quaterthiophene-5-carboxylic acid 3,4,5-tridodecyloxybenzyl ester

C₆₁H₉₀O₆S₄