((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

Base Information

Chemical Name:((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide
CAS No.:81027-76-1
Molecular Formula:C₂₉H₃₄O₂P*I
Molecular Weight:572.466
Hs Code.:

Synonyms:((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

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Chemical Property of ((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

Chemical Property:

Purity/Quality:

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Technology Process of ((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

There total 9 articles about ((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2-((E)-7-Iodo-3-methyl-hept-3-enyl)-[1,3]dioxolane

: 603-35-0
triphenylphosphine

: 81027-76-1
((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In benzene; at 55 ℃; dark;
DOI:10.1021/ja00371a062

Reference yield:

: 35334-61-3
(E)-5-(1,3-dioxolan-2-yl)-3-methylpent-2-enyl acetate

: 81027-76-1
((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

Guidance literature:: Multi-step reaction with 7 steps

1: TEA / -80 °C

2: NaOH / methanol; H₂O / Heating

3: 1.) n-BuLi / 1.) THF, -78 deg C, 2.) 0 deg C

4: 49 percent / Ca/NH₃ / tetrahydrofuran / -78 °C

5: pyridine / 0 °C

6: NaI / acetone / Ambient temperature

7: EtN(i-Pr)2 / benzene / 55 °C / dark

With pyridine; sodium hydroxide; n-butyllithium; TEA; ammonia; calcium; N-ethyl-N,N-diisopropylamine; sodium iodide; In tetrahydrofuran; methanol; water; acetone; benzene;
DOI:10.1021/ja00371a062

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 81027-76-1
((E)-7-[1,3]Dioxolan-2-yl-5-methyl-hept-4-enyl)-triphenyl-phosphonium; iodide

Guidance literature:: Multi-step reaction with 9 steps

1: oxidation

2: p-CH₃C₆H₄SO₃H

3: TEA / -80 °C

4: NaOH / methanol; H₂O / Heating

5: 1.) n-BuLi / 1.) THF, -78 deg C, 2.) 0 deg C

6: 49 percent / Ca/NH₃ / tetrahydrofuran / -78 °C

7: pyridine / 0 °C

8: NaI / acetone / Ambient temperature

9: EtN(i-Pr)2 / benzene / 55 °C / dark

With pyridine; sodium hydroxide; n-butyllithium; TEA; ammonia; calcium; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; sodium iodide; In tetrahydrofuran; methanol; water; acetone; benzene;
DOI:10.1021/ja00371a062