(1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1)

Base Information

• Chemical Name: (1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1)
• CAS No.: 35238-97-2
• Molecular Formula: C45H44Cl2F6P3Rh4*
• Molecular Weight: 880.635
• Mol file: 35238-97-2.mol

Synonyms:(1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1);(1,5-cyclooctadiene)bis(triphenylphos-phine)rhodi;(1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOS-PH INE)RHODIUM(I) PF6 CH2CL2 (1:1);(1,5-cyclooctadiene)bis(triphenylphosphine)rhodium(i) hexafluorophosphate dichloromethane complex (1:1);(1,5-cyclooctadiene)bis(triphenylphosphine)rhodium(I) PF6/

Chemical Property of (1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1)

Chemical Property:

• Melting Point: 215 °C(lit.)
• PSA: 40.77000
• LogP: 14.07110

Purity/Quality:

98%,99%, ^*data from raw suppliers

(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Catalyst for:Polycyclotrimerization reactionsHydrosilylation and hydrogenation reactionsHydroformylation reactionsRegioselective di- and trisilylation reactionsMannich and nitro-Mannich reactionsReductive alkylation reactions

Technology Process of (1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1)

There total 1 articles about (1,5-CYCLOOCTADIENE)BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE DICHLOROMETHANE COMPLEX (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((C6H5)2PC6H4P(C6H5)2CHSOC6H4CH3)Rh(C8H12)(1+)*PF6(1-)=(((C6H5)2PC6H4P(C6H5)2CHSOC6H4CH3)Rh(C8H12))PF6 (628340-12-5,628340-10-3) + triphenylphosphine (603-35-0) → Shrock-Osborn catalyst (35238-97-2)

Guidance literature:

With hexafluorophosphoric acid; In dichloromethane; water; under N2 atm. to soln. Rh complex and PPh3 in CH2Cl2 at -20°C 65%aq. HPF6 was added, 20 min at -20°C and 30 min at room temp.; solvent was evapd.;

DOI:10.1021/om030343g

Reference yield: 90.0%

[(1,5-cyclooctadiene)Rh(PPh3)2]PF6 (35238-97-2) + dicarbonyl(η5-cyclopentadienyl)tolylcarbyne tungsten → (WRh(μ-CC6H4Me-4)(CO)2(PPh3)2(η-C5H5))(PF6)

Guidance literature:

In dichloromethane; stirring for 1h (room temp.), solvent reducing (vacuo); Et2O was added, crystn., elem. anal.;

DOI:10.1016/0022-328X(88)80276-6

Reference yield: 89.0%

quinoline (91-22-5) + [(1,5-cyclooctadiene)Rh(PPh3)2]PF6 (35238-97-2) → Rh(C8H12)(P(C6H5)3)(C9NH7)(1+)*PF6(1-)={Rh(C8H12)(P(C6H5)3)(C9NH7)}PF6 (152639-57-1)

Guidance literature:

In dichloromethane; to a soln. of the Rh-complex in CH2Cl2 was added quinoline, mixt. was stirred under N2 or H2 at room temp. for 30 min; vol. was reduced, addn. of Et2O, filtered, washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1021/om00035a013

upstream raw materials:

((C₆H₅)2PC₆H₄P(C₆H₅)2CHSOC₆H₄CH₃)Rh(C₈H₁₂)⁽¹⁺⁾*PF₆^(1-)=(((C₆H₅)2PC₆H₄P(C₆H₅)2CHSOC₆H₄CH₃)Rh(C₈H₁₂))PF₆

triphenylphosphine

Downstream raw materials:

{Rh(η4-Me2C4H2SiMe(allyl))(PPh3)2}(PF6)

{Rh(η4-Me2C4H2SiMePh)(PPh3)2}(PF6)

{Rh(η4-Me2C4H2Si(allyl)2)(PPh3)2}(PF6)

Rh(C₈H₁₂)(P(C₆H₅)3)(C₉NH₇)⁽¹⁺⁾*PF₆^(1-)={Rh(C₈H₁₂)(P(C₆H₅)3)(C₉NH₇)}PF₆

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