CH₃OC(O)Co(CO)3P(C₆H₅)3

Base Information

• Chemical Name: CH₃OC(O)Co(CO)3P(C₆H₅)3
• CAS No.: 83269-57-2
• Molecular Formula: C₂₃H₁₈CoO₅P
• Molecular Weight: 464.36
• Mol file: 83269-57-2.mol

Synonyms:CH₃OC(O)Co(CO)3P(C₆H₅)3

Chemical Property of CH₃OC(O)Co(CO)3P(C₆H₅)3

Chemical Property:

Purity/Quality:

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Technology Process of CH₃OC(O)Co(CO)3P(C₆H₅)3

There total 2 articles about CH₃OC(O)Co(CO)3P(C₆H₅)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Me-oxycarbonylcobalt tetracarbonyl → CH3OC(O)Co(CO)3P(C6H5)3 (83269-57-2)

Guidance literature:

With PPh₃; In diethyl ether; byproducts: CO; Co-complex was condensed into an ether soln. of PPh3;

DOI:10.1021/ja00386a068

Reference yield:

CoI(CO)3(P(C6H5)3) (36158-67-5,14376-37-5) + methanolate (3315-60-4) → {Co(CO)3P(C6H5)3}1(1-) (53513-20-5) + CH3OC(O)Co(CO)3P(C6H5)3 (83269-57-2)

Guidance literature:

With 15-crown-5 or 18-crown-6; In tetrahydrofuran; under Ar, ICo(CO)3PPh3 dissolved in THF, Na or K alkoxide and 15-crown-5 or 18-crown-6 resp. added, stirred at 20-25°C for 1 h; n-heptane added, THF evapd. in vac., filtered, evapd. in vac., recrystd. from Et2O/pentane at -78°C;

DOI:10.1021/om00128a006

upstream raw materials:

CoI(CO)3(P(C₆H₅)3)

methanolate