Technology Process of 4-<8'Z,11'Z-heptadecadienyl>catechol
There total 9 articles about 4-<8'Z,11'Z-heptadecadienyl>catechol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
acetic acid;
In
water;
at 110 ℃;
for 18h;
- Guidance literature:
-
Multi-step reaction with 9 steps
1: 86 percent / butyl-lithium / hexane; tetrahydrofuran / -78 °C
2: 82 percent / lithium aluminium hydride / diethyl ether / 6 h
3: 100 percent / thionyl chloride, pyridine / benzene / 3 h
4: 90 percent / toluene / 96 h / Heating
5: 1.) butyl lithium, 2.) H2 / palladized charcoal (10percent) / 1.) hexane, THF, 18 h, 2.) ethyl acetate
6: 100 percent / lithium aluminium hydride / diethyl ether / 3 h
7: 92 percent / pyridinium chlorochromate, sodium acetate / CH2Cl2 / 2.5 h
8: 85 percent / butyl-lithium, haxamethylphosphoric triamide / hexane; tetrahydrofuran / 0.5 h / -78 °C
9: 87 percent / acetic acid / H2O / 18 h / 110 °C
With
pyridine; lithium aluminium tetrahydride; n-butyllithium; thionyl chloride; hydrogen; sodium acetate; acetic acid; phosphoramide; pyridinium chlorochromate;
palladium on activated charcoal;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; toluene; benzene;
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 90 percent / toluene / 96 h / Heating
2: 1.) butyl lithium, 2.) H2 / palladized charcoal (10percent) / 1.) hexane, THF, 18 h, 2.) ethyl acetate
3: 100 percent / lithium aluminium hydride / diethyl ether / 3 h
4: 92 percent / pyridinium chlorochromate, sodium acetate / CH2Cl2 / 2.5 h
5: 85 percent / butyl-lithium, haxamethylphosphoric triamide / hexane; tetrahydrofuran / 0.5 h / -78 °C
6: 87 percent / acetic acid / H2O / 18 h / 110 °C
With
lithium aluminium tetrahydride; n-butyllithium; hydrogen; sodium acetate; acetic acid; phosphoramide; pyridinium chlorochromate;
palladium on activated charcoal;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; water; toluene;
