methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

Base Information

Chemical Name:methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside
CAS No.:1391992-93-0
Molecular Formula:C₄₈H₄₇NO₁₂
Molecular Weight:829.901
Hs Code.:

Synonyms:methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

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Technology Process of methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

There total 1 articles about methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 67381-21-9
methyl 2,3-di-O-benzyl-4,6-dideoxy-4-hydroxyimino-α-D-glucopyranoside

: 1391992-92-9
2,3,4-tri-O-benzyl-L-rhamnopyranosyl ortho-hex-1-ynylbenzoate

: 1391992-93-0
methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

: 1391992-94-1
methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(E)-hydroxyimino)-α-D-glucopyranoside

Guidance literature:: With triphenylphosphinegold(I) triflate; In dichloromethane; at 20 ℃; for 3h; optical yield given as %de; Molecular sieve; Inert atmosphere;
DOI:10.1021/ol301863j

Reference yield: 86.0%

: 1391992-93-0
methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

: 1391993-12-6
methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosylhydroxyamino)-α-D-galactopyranoside

Guidance literature:: With boron trifluoride diethyl etherate; sodium cyanoborohydride; In dichloromethane; at -40 - 0 ℃; for 3h; stereoselective reaction;
DOI:10.1021/ol301863j

Reference yield:

: 1391992-93-0
methyl 2,3-di-O-benzyl-4,6-dideoxy-4-(2',3',4'-tri-O-benzoyl-α-L-rhamnopyranosyl-(Z)-hydroxyimino)-α-D-glucopyranoside

: 1391993-15-9
C₃₄H₃₇NO₁₂

Guidance literature:: Multi-step reaction with 2 steps

1: boron trifluoride diethyl etherate; sodium cyanoborohydride / dichloromethane / 3 h / -40 - 0 °C

2: boron trifluoride diethyl etherate; ethanethiol / dichloromethane / 20 °C

With boron trifluoride diethyl etherate; sodium cyanoborohydride; ethanethiol; In dichloromethane;
DOI:10.1021/ol301863j