C₆₄H₁₁₆O₁₆Si₄

Base Information

Chemical Name:C₆₄H₁₁₆O₁₆Si₄
CAS No.:1449432-43-2
Molecular Formula:C₆₄H₁₁₆O₁₆Si₄
Molecular Weight:1253.96
Hs Code.:

C<sub>64</sub>H<sub>116</sub>O<sub>16</sub>Si<sub>4</sub>

Synonyms:C₆₄H₁₁₆O₁₆Si₄

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Chemical Property of C₆₄H₁₁₆O₁₆Si₄

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Technology Process of C₆₄H₁₁₆O₁₆Si₄

There total 15 articles about C₆₄H₁₁₆O₁₆Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1449432-35-2
(2S)-2-[(3aS,5S,7aS)-5-[(1,1-Dimethylethyl)dimethylsilyl]oxyhexahydro-7a-methyl-(3H)-inden-1-yl]propan-1-al

: 1449432-43-2
C₆₄H₁₁₆O₁₆Si₄

Guidance literature:: Multi-step reaction with 8 steps

1.1: tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

2.1: dipyridinium dichromate / dichloromethane / 19 h / 20 °C / Inert atmosphere; Molecular sieve

3.1: toluene-4-sulfonic acid; orthoformic acid triethyl ester / dichloromethane / 64 h / 20 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

5.1: osmium(VIII) oxide; pyridine / diethyl ether / 3 h / 20 °C / Inert atmosphere

5.2: Inert atmosphere

6.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

6.2: -78 - 20 °C / Inert atmosphere

7.1: sodium tetrahydroborate; cerium(III) chloride monohydrate / tetrahydrofuran / 5 h / 0 °C

8.1: dichloromethane / 0.25 h / 20 °C / Inert atmosphere; Molecular sieve

8.2: 0.5 h / -20 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; sodium tetrahydroborate; osmium(VIII) oxide; dipyridinium dichromate; oxalyl dichloride; cerium(III) chloride monohydrate; toluene-4-sulfonic acid; dimethyl sulfoxide; orthoformic acid triethyl ester; In tetrahydrofuran; diethyl ether; dichloromethane; 6.1: |Swern Oxidation / 6.2: |Swern Oxidation;
DOI:10.1016/j.tet.2013.06.105

Reference yield:

: 118141-48-3
(3aR,7aS)-1,2,3a,4,5,6,7,7a-octahydro-7a-methyl<1H>inden-1,5-dione

: 1449432-43-2
C₆₄H₁₁₆O₁₆Si₄

Guidance literature:: Multi-step reaction with 15 steps

1.1: oxalic acid / acetonitrile / 1.5 h / 20 °C / Inert atmosphere

2.1: tetrahydrofuran / 15 h / 20 °C / Inert atmosphere

3.1: toluene-4-sulfonic acid / acetone / 1.5 h / 20 °C / Inert atmosphere

4.1: sodium tetrahydroborate / dichloromethane; methanol / 0.75 h / 0 °C / Inert atmosphere

5.1: 2,6-dimethylpyridine / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

6.1: boron trifluoride diethyl etherate / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

7.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 3.5 h / 20 °C / Inert atmosphere

8.1: tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

9.1: dipyridinium dichromate / dichloromethane / 19 h / 20 °C / Inert atmosphere; Molecular sieve

10.1: toluene-4-sulfonic acid; orthoformic acid triethyl ester / dichloromethane / 64 h / 20 °C / Inert atmosphere

11.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

12.1: osmium(VIII) oxide; pyridine / diethyl ether / 3 h / 20 °C / Inert atmosphere

12.2: Inert atmosphere

13.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

13.2: -78 - 20 °C / Inert atmosphere

14.1: sodium tetrahydroborate; cerium(III) chloride monohydrate / tetrahydrofuran / 5 h / 0 °C

15.1: dichloromethane / 0.25 h / 20 °C / Inert atmosphere; Molecular sieve

15.2: 0.5 h / -20 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; sodium tetrahydroborate; osmium(VIII) oxide; dipyridinium dichromate; oxalyl dichloride; cerium(III) chloride monohydrate; boron trifluoride diethyl etherate; oxalic acid; toluene-4-sulfonic acid; dimethyl sulfoxide; orthoformic acid triethyl ester; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; dimethyl sulfoxide; acetone; acetonitrile; 2.1: |Wittig Olefination / 13.1: |Swern Oxidation / 13.2: |Swern Oxidation;
DOI:10.1016/j.tet.2013.06.105

Reference yield:

: 1044141-08-3
(3a'S,7a'S)-7a'-methyloctahydrospiro([1,3]dioxolane-2,5'-inden)-1'(6'H)-one

: 1449432-43-2
C₆₄H₁₁₆O₁₆Si₄

Guidance literature:: Multi-step reaction with 14 steps

1.1: tetrahydrofuran / 15 h / 20 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / acetone / 1.5 h / 20 °C / Inert atmosphere

3.1: sodium tetrahydroborate / dichloromethane; methanol / 0.75 h / 0 °C / Inert atmosphere

4.1: 2,6-dimethylpyridine / dichloromethane / 2.5 h / 20 °C / Inert atmosphere

5.1: boron trifluoride diethyl etherate / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

6.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 3.5 h / 20 °C / Inert atmosphere

7.1: tetrahydrofuran / 1 h / 0 °C / Inert atmosphere

8.1: dipyridinium dichromate / dichloromethane / 19 h / 20 °C / Inert atmosphere; Molecular sieve

9.1: toluene-4-sulfonic acid; orthoformic acid triethyl ester / dichloromethane / 64 h / 20 °C / Inert atmosphere

10.1: 2,6-dimethylpyridine / dichloromethane / 1.5 h / 20 °C / Inert atmosphere

11.1: osmium(VIII) oxide; pyridine / diethyl ether / 3 h / 20 °C / Inert atmosphere

11.2: Inert atmosphere

12.1: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 0.5 h / -78 °C / Inert atmosphere

12.2: -78 - 20 °C / Inert atmosphere

13.1: sodium tetrahydroborate; cerium(III) chloride monohydrate / tetrahydrofuran / 5 h / 0 °C

14.1: dichloromethane / 0.25 h / 20 °C / Inert atmosphere; Molecular sieve

14.2: 0.5 h / -20 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; sodium tetrahydroborate; osmium(VIII) oxide; dipyridinium dichromate; oxalyl dichloride; cerium(III) chloride monohydrate; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; dimethyl sulfoxide; orthoformic acid triethyl ester; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; dimethyl sulfoxide; acetone; 1.1: |Wittig Olefination / 12.1: |Swern Oxidation / 12.2: |Swern Oxidation;
DOI:10.1016/j.tet.2013.06.105