rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane

Base Information

• Chemical Name: rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane
• CAS No.: 1392009-66-3
• Molecular Formula: C₁₈H₂₈O₂Si
• Molecular Weight: 304.505
• Mol file: 1392009-66-3.mol

Synonyms:rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane

Chemical Property of rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane

There total 1 articles about rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

rac-1-[(tert-butyldimethylsilyl)oxy]pent-3-yn-2-ol (1314558-94-5) → rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane (1392009-66-3)

Guidance literature:

rac-1-[(tert-butyldimethylsilyl)oxy]pent-3-yn-2-ol; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.25h; Inert atmosphere;

In tetrahydrofuran; mineral oil; at 20 ℃; for 4h; Inert atmosphere;

DOI:10.1021/ja305532y

Reference yield: 57.0%

rac-((2-(benzyloxy)pent-3-yn-1-yl)oxy)(tert-butyl)dimethylsilane (1392009-66-3) → rac-4-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)pentane-2,3-dione (1392009-75-4)

Guidance literature:

With sodium periodate; ruthenium (IV) oxide monohydrate; water; In tetrachloromethane; acetonitrile; at 20 ℃; for 0.333333h; Inert atmosphere;

DOI:10.1021/ja305532y

upstream raw materials:

rac-1-[(tert-butyldimethylsilyl)oxy]pent-3-yn-2-ol

Downstream raw materials:

rac-4-(benzyloxy)-5-((tert-butyldimethylsilyl)oxy)pentane-2,3-dione