N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

Base Information

Chemical Name:N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide
CAS No.:153391-80-1
Molecular Formula:C₁₇H₂₃NO₅S
Molecular Weight:353.439
Hs Code.:

Synonyms:N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

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Technology Process of N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

There total 2 articles about N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 155940-97-9
(Z)-N-(but-2-en-1-yl)-4-methylbenzenesulfonamide

: 137718-73-1
(Z)-(4-bromobut-2-en-1-yl) methyl carbonate

: 153391-80-1
N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; for 14h; Ambient temperature;
DOI:10.1002/hlca.19930760618

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 153391-80-1
N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / pyridine / CH₂Cl₂ / 16 h / Ambient temperature

2: 86 percent / NaH in oil (60percent) / dimethylformamide / 14 h / Ambient temperature

With pyridine; sodium hydride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/hlca.19930760618

Reference yield:

: 153391-80-1
N-<(Z)-(but-2-enyl)>-N-<(Z)-4-((methoxycarbonyl)oxy)but-2-enyl>-p-toluenesulfonamide

: cis-tetrahydro-1-(p-toluenesulfonyl)-3,4-divinylpyroles

: trans-tetrahydro-1-(p-toluenesulfonyl)-3,4-divinylpyroles

Guidance literature:: With tris(2,4,6-trimethoxyphenyl)phosphine; rhodium hydrido (PEt₃)3 complex; In acetic acid; at 80 ℃; for 12h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1002/hlca.19930760618