11-Dodecenyl acetate

Base Information

• Chemical Name: 11-Dodecenyl acetate
• CAS No.: 35153-10-7
• Molecular Formula: C14H26 O2
• Molecular Weight: 226.359
• Hs Code.: 2915390090
• DSSTox Substance ID: DTXSID00334438
• Nikkaji Number: J680G
• Wikidata: Q63391666
• Metabolomics Workbench ID: 3905
• Mol file: 35153-10-7.mol

Synonyms:11-Dodecenyl acetate;11-Dodecen-1-yl acetate;35153-10-7;dodec-11-enyl acetate;11-Dodecen-1-ol acetate;11-Dodecenyl acetate #;SCHEMBL592903;11-DDA;DTXSID00334438;CHEBI:179346;LMFA07010260;AKOS024342583;11-Dodecenyl acetate CAS 35153-10-7;FT-0730484;Q63391666

Chemical Property of 11-Dodecenyl acetate

Chemical Property:

• Vapor Pressure: 0.00406mmHg at 25°C
• Refractive Index: 1.442
• Boiling Point: 279.3±9.0℃ (760 Torr)
• Flash Point: 116.1±14.5℃
• PSA: 26.30000
• Density: 0.876±0.06 g/cm3 (20 ºC 760 Torr)
• LogP: 4.24640
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 226.193280068
• Heavy Atom Count: 16
• Complexity: 176

Purity/Quality:

98%,99%, ^*data from raw suppliers

11-DODECENYL ACETATE ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=O)OCCCCCCCCCCC=C
• Uses: 11-Dodecenyl Acetate is a sex pheromone that plays a major role in reproduction in plants.

Technology Process of 11-Dodecenyl acetate

There total 2 articles about 11-Dodecenyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bromoethyl acetate (927-68-4) + 10-chloro-1-decene (1002-70-6) → 1-Decene (872-05-9,17438-89-0,25189-70-2) + 11-Dodecenyl acetate (35153-10-7)

Guidance literature:

10-chloro-1-decene; With magnesium; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; toluene; at 70 ℃; for 20h;

bromoethyl acetate; In tetrahydrofuran; toluene; at 20 ℃; for 3.5h;

Reference yield:

9-Decen-1-ol (13019-22-2) → 1-Decene (872-05-9,17438-89-0,25189-70-2) + 11-Dodecenyl acetate (35153-10-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 1,3,5-trichloro-2,4,6-triazine / N,N-dimethyl-formamide / 3 h / 0 - 20 °C / Inert atmosphere

2.1: sodium bis(2-methoxyethoxy)aluminium dihydride; magnesium / tetrahydrofuran; toluene / 20 h / 70 °C

2.2: 3.5 h / 20 °C

With 1,3,5-trichloro-2,4,6-triazine; magnesium; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; N,N-dimethyl-formamide; toluene;

Reference yield: 98.0%

11-Dodecenyl acetate (35153-10-7) → dodec-11-en-1-ol (35289-31-7)

Guidance literature:

With potassium hydroxide; In methanol; water; for 8h; Heating;

DOI:10.1007/BF00580036

upstream raw materials:

9-Decen-1-ol

bromoethyl acetate

10-chloro-1-decene

Downstream raw materials:

C₂₀H₃₁Cl₃O₂Se

dodec-11-en-1-ol

9,11-dodecadien-1-yl acetate

11-dodecyn-1-ol