O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Base Information

Chemical Name:O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol
CAS No.:1334671-97-4
Molecular Formula:C₅₄H₆₇N₃O₁₁
Molecular Weight:934.139
Hs Code.:

Synonyms:O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Suppliers and Price of O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

There total 2 articles about O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1332524-18-1
phenyl 3,4,6-tri-O-benzoyl-1-thio-α-D-mannopyranoside

: 1334671-85-0
(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

: 1334671-97-4
O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Guidance literature:: phenyl 3,4,6-tri-O-benzoyl-1-thio-α-D-mannopyranoside; (2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol; With N-iodo-succinimide; In dichloromethane; at 20 ℃; for 0.333333h; Molecular sieve;

With silver trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 1h; Molecular sieve;
DOI:10.1016/j.carres.2011.06.027

Reference yield:

: (2S,3R,4E)-2-azido-3-O-benzoyl-4-eicosene-1,3-diol

: 1334671-97-4
O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Guidance literature:: Multi-step reaction with 2 steps

1.1: palladium on activated charcoal; hydrogen / methanol / 3 h

2.1: N-iodo-succinimide / dichloromethane / 0.33 h / 20 °C / Molecular sieve

2.2: 1 h / 0 °C / Molecular sieve

With N-iodo-succinimide; palladium on activated charcoal; hydrogen; In methanol; dichloromethane;
DOI:10.1016/j.carres.2011.06.027

Reference yield: 87.0%

: 1334671-88-3
phenyl 4,6-di-O-benzyl-2-deoxy-3-O-p-methoxybenzyl-1-thio-2-trichloroacetamido-β-D-glucopyranoside

: 1334671-97-4
O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

: 1334671-98-5
O-(4,6-di-O-benzyl-2-deoxy-3-O-p-methoxybenzyl-2-trichloroacetamido-β-D-glucopyranosyl)-(1->2)-O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol

Guidance literature:: phenyl 4,6-di-O-benzyl-2-deoxy-3-O-p-methoxybenzyl-1-thio-2-trichloroacetamido-β-D-glucopyranoside; O-(3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->1)-(2S,3R)-2-azido-3-O-benzoyl-1,3-eicosanediol; With N-iodo-succinimide; In dichloromethane; at 20 ℃; for 0.333333h; Molecular sieve;

With trifluorormethanesulfonic acid; In dichloromethane; at -15 ℃; for 1h; Molecular sieve;
DOI:10.1016/j.carres.2011.06.027