4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene

Base Information

• Chemical Name: 4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene
• CAS No.: 870836-65-0
• Molecular Formula: C₂₇H₂₈N₆O₄
• Molecular Weight: 500.557
• Mol file: 870836-65-0.mol

Synonyms:4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene

Chemical Property of 4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene

There total 2 articles about 4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

4-(N-methyl-N-(4-hydroxybutyl)amino)-4'-(4-nitrophenylazo)azobenzene + Methacryloyl chloride (920-46-7,26937-45-1) → 4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene (870836-65-0)

Guidance literature:

With triethylamine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1021/ma051455h

Reference yield:

N-(4-hydroxybutyl)-N-methylaniline (169556-13-2) → 4-{(4-methacryloyloxybutyl)methylamino}-4'-(4-nitrophenylazo)azobenzene (870836-65-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: conc. HCl; aq. NaNO₂ / dimethylformamide / 2 h / 0 °C

1.2: acetic acid / dimethylformamide / 20 h / 0 - 20 °C

2.1: 81 percent / Et₃N / tetrahydrofuran / 0 - 20 °C

With hydrogenchloride; triethylamine; sodium nitrite; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1021/ma051455h

upstream raw materials:

Methacryloyl chloride

N-(4-hydroxybutyl)-N-methylaniline