Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

Base Information

Chemical Name:Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester
CAS No.:208585-92-6
Molecular Formula:C₃₁H₄₅NO₅SSi
Molecular Weight:571.854
Hs Code.:

Synonyms:Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

Suppliers and Price of Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

There total 1 articles about Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 54125-02-9
danishefsky's diene

: 208585-90-4
Benzyl-[4-benzyloxy-3-(2-oxo-2-phenyl-ethylsulfanyl)-butyl]-carbamic acid tert-butyl ester

: 208585-92-6
Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

Guidance literature:: In benzene; at 22 - 24 ℃; for 8h; Irradiation;
DOI:10.1021/ja973464e

Reference yield:

: 208585-92-6
Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

: (Z)-4-Benzyloxy-6-benzyloxymethyl-1-methyl-1,3,4,8-tetrahydro-2H-azocin-5-one

Guidance literature:: Multi-step reaction with 12 steps

1: TFA / CHCl₃ / 5 h / Ambient temperature

2: 97 percent / L-Selectride / tetrahydrofuran / 3 h / Ambient temperature

3: 88 percent / NaH, imidazole, Bu₄NI / tetrahydrofuran; dimethylformamide / 11 h / 0 - 20 °C

4: NaBH₃CN, AcOH / various solvent(s) / 48 h / Ambient temperature

5: DBU / benzene / 14 h / Ambient temperature

6: 95 percent / tetrahydrofuran / 16 h / Ambient temperature

7: tetrabutylammonium oxone / CH₂Cl₂ / 1.5 h / 0 °C

8: CaCO₃ / xylene / 0.25 h / Heating

9: 96 percent / LiAlH₄ / tetrahydrofuran / 8 h / Ambient temperature

10: OsO₄ / Ambient temperature

11: 53 percent / K₃Fe(CN)6, OsO₄ / 2-methyl-propan-2-ol / 0.92 h

12: 1.) MeO₂CN^--SO₂N⁺Et₃, 3.) H₂O

With 1H-imidazole; osmium(VIII) oxide; lithium aluminium tetrahydride; Burgess Reagent; Oxone tetrabutylammonium salt; water; tetra-(n-butyl)ammonium iodide; L-Selectride; sodium hydride; sodium cyanoborohydride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; trifluoroacetic acid; calcium carbonate; potassium hexacyanoferrate(III); In tetrahydrofuran; dichloromethane; chloroform; N,N-dimethyl-formamide; xylene; tert-butyl alcohol; benzene;
DOI:10.1021/ja973464e

Reference yield:

: 208585-92-6
Benzyl-[2-(2-benzyloxymethyl-6-methoxy-4-trimethylsilanyloxy-3,6-dihydro-2H-thiopyran-2-yl)-ethyl]-carbamic acid tert-butyl ester

: (4R,5R,6S)-6-Benzyloxy-4-benzyloxymethyl-1-methyl-azocane-4,5-diol

Guidance literature:: Multi-step reaction with 10 steps

1: TFA / CHCl₃ / 5 h / Ambient temperature

2: 97 percent / L-Selectride / tetrahydrofuran / 3 h / Ambient temperature

3: 88 percent / NaH, imidazole, Bu₄NI / tetrahydrofuran; dimethylformamide / 11 h / 0 - 20 °C

4: NaBH₃CN, AcOH / various solvent(s) / 48 h / Ambient temperature

5: DBU / benzene / 14 h / Ambient temperature

6: 95 percent / tetrahydrofuran / 16 h / Ambient temperature

7: tetrabutylammonium oxone / CH₂Cl₂ / 1.5 h / 0 °C

8: CaCO₃ / xylene / 0.25 h / Heating

9: 96 percent / LiAlH₄ / tetrahydrofuran / 8 h / Ambient temperature

10: OsO₄ / Ambient temperature

With 1H-imidazole; osmium(VIII) oxide; lithium aluminium tetrahydride; Oxone tetrabutylammonium salt; tetra-(n-butyl)ammonium iodide; L-Selectride; sodium hydride; sodium cyanoborohydride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; trifluoroacetic acid; calcium carbonate; In tetrahydrofuran; dichloromethane; chloroform; N,N-dimethyl-formamide; xylene; benzene;
DOI:10.1021/ja973464e