tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron

Base Information

• Chemical Name: tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron
• CAS No.: 387872-28-8
• Molecular Formula: C₁₇H₁₉FeO₇P
• Molecular Weight: 422.154
• Mol file: 387872-28-8.mol

Synonyms:tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron

Chemical Property of tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron

There total 1 articles about tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1-4-η-3-tert-butyldimethylsilyloxy-1-phenyl-1,3-butadiene)tricarbonyliron + diethyl chlorophosphate (814-49-3) → tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron (387872-28-8)

Guidance literature:

(1-4-η-3-tert-butyldimethylsilyloxy-1-phenyl-1,3-butadiene)tricarbonyliron; With cesium fluoride; In acetonitrile; at 20 ℃; for 0.25h; Inert atmosphere;

diethyl chlorophosphate; In acetonitrile; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c5cc00870k

Reference yield: 92.0%

tricarbonyl(1-4-η-3-diethoxyphosphoryloxy-1-phenyl-1,3-butadiene)iron (387872-28-8) → C4H3C6H5OHPO(OCH2CH3)2Fe(CO)3 (387872-48-2)

Guidance literature:

With LiN(CH(CH₃)2)2; In tetrahydrofuran; reaction of iron complex with lithium compd. in THF at -78°C for 1 min;

DOI:10.1021/ja016958r

upstream raw materials:

diethyl chlorophosphate

Downstream raw materials:

C₄H₃C₆H₅OHPO(OCH₂CH₃)2Fe(CO)3