cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

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Chemical Name:cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane
CAS No.:128806-70-2
Molecular Formula:C₃₁H₄₀O₂S
Molecular Weight:476.723
Hs Code.:

Synonyms:cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

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Chemical Property of cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

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Technology Process of cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

There total 7 articles about cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 128806-69-9
cis-1-methanesulfonyloxymethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

: 108-98-5
thiophenol

: 128806-70-2
cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Guidance literature:: With potassium ethoxide; In ethanol; for 96h; Ambient temperature;
DOI:10.1016/S0040-4020(01)85431-4

Reference yield:

: 105-87-3,8022-83-1
3,7-dimethyl-2E,6-octadien-1-yl acetate

: 128806-70-2
cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Guidance literature:: Multi-step reaction with 5 steps

1: 8.4 percent / ZnCl₂ / nitromethane / 3 h / -20 °C

2: 90 percent / pyridine / CH₂Cl₂ / 24 h / 0 °C

3: 55 percent / 1.) POCl₃, pyridine, 2.) 1N NaOH / 1.) room temperature, overnight, 2.) ethanol, 0 deg C, 4 h

4: triethylamine / CH₂Cl₂ / -10 °C

5: 75 percent / potassium ethoxide / ethanol / 96 h / Ambient temperature

With pyridine; sodium hydroxide; potassium ethoxide; triethylamine; zinc(II) chloride; trichlorophosphate; In nitromethane; ethanol; dichloromethane;
DOI:10.1016/S0040-4020(01)85431-4

Reference yield:

: 108287-02-1,108287-03-2,108287-04-3,108291-85-6
2-r-Acetoxymethyl-1,3,3-trimethyl-4-c(3-methyl-2-buten-1-yl)-1-t-cyclohexanol

: 128806-70-2
cis-1-phenylthiomethyl-2,2-dimethyl-6-methylene-3-<4-(2,4,6-trimethylbenzoyloxy)-3-methyl-2-E-buten-1-yl>-cyclohexane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) SeO₂, t-BuOOH, salicylic acid, 2.) NaBH₄ / 1.) CH₂Cl₂, 30 h, room temperature, 2.) MeOH, 0 deg C, 30 min

2: 90 percent / pyridine / CH₂Cl₂ / 24 h / 0 °C

3: 55 percent / 1.) POCl₃, pyridine, 2.) 1N NaOH / 1.) room temperature, overnight, 2.) ethanol, 0 deg C, 4 h

4: triethylamine / CH₂Cl₂ / -10 °C

5: 75 percent / potassium ethoxide / ethanol / 96 h / Ambient temperature

With pyridine; tert.-butylhydroperoxide; sodium hydroxide; sodium tetrahydroborate; selenium(IV) oxide; potassium ethoxide; triethylamine; salicylic acid; trichlorophosphate; In ethanol; dichloromethane;
DOI:10.1016/S0040-4020(01)85431-4