(S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

Base Information

Chemical Name:(S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol
CAS No.:24707-87-7
Molecular Formula:C₁₆H₂₂O₅
Molecular Weight:294.348
Hs Code.:

Synonyms:(S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

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Chemical Property of (S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

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Technology Process of (S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

There total 9 articles about (S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: (S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethyl 4-nitrobenzoate

: 24707-87-7
(S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

Guidance literature:: With methanol; potassium carbonate; at 20 ℃; for 0.5h;

Reference yield:

: 78784-99-3
(R)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

: 24707-87-7
(S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: diethylazodicarboxylate; triphenylphosphine / tetrahydrofuran / 10 h / 0 - 18 °C / Inert atmosphere

2: methanol; potassium carbonate / 0.5 h / 20 °C

With methanol; potassium carbonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran;

Reference yield:

: 16667-96-2
1,2,5,6-di-O-isopropylidene-α-D-glucofuranose-3-O-(S-methylxanthate)

: 24707-87-7
(S)-2-(benzyloxy)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

Guidance literature:: Multi-step reaction with 7 steps

1: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / 6 h / 120 °C / Inert atmosphere

2: acetic acid / water / 16 h / 20 °C

3: pyridine / Petroleum ether / 12 h / 0 - 20 °C

4: potassium hexamethylsilazane / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

5: sodium hydride / mineral oil; 1,2-dimethoxyethane / 4 h / 0 - 60 °C / Inert atmosphere

6: diethylazodicarboxylate; triphenylphosphine / tetrahydrofuran / 10 h / 0 - 18 °C / Inert atmosphere

7: methanol; potassium carbonate / 0.5 h / 20 °C

With pyridine; methanol; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; potassium hexamethylsilazane; sodium hydride; potassium carbonate; acetic acid; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; 1,2-dimethoxyethane; water; toluene; mineral oil; Petroleum ether;