(E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

Base Information

Chemical Name:(E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene
CAS No.:1638136-91-0
Molecular Formula:C₂₉H₃₂O
Molecular Weight:396.572
Hs Code.:

Synonyms:(E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

Suppliers and Price of (E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

There total 5 articles about (E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 1638136-77-2
(E)-N-((E)-3-bromo-2-methylbut-2-en-1-yl)-N`-(2,2-dimethyl-3-(trityloxy)propylidene)-4-methylbenzenesulfonohydrazide

: 1638136-91-0
(E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

: 1638136-92-1
(Z)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; at 80 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1002/anie.201403234

Reference yield:

: 80-59-1
Tiglic acid

: 1638136-91-0
(E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

: 1638136-92-1
(Z)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

Guidance literature:: Multi-step reaction with 4 steps

1.1: bromine / chloroform / 1.5 h / 45 °C / Inert atmosphere

1.2: 3 h / Inert atmosphere

2.1: lithium aluminium tetrahydride / tetrahydrofuran

3.1: sodium sulfate / tetrahydrofuran

4.1: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / benzene / 80 °C / Inert atmosphere

With lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); bromine; tri-n-butyl-tin hydride; sodium sulfate; In tetrahydrofuran; chloroform; benzene;
DOI:10.1002/anie.201403234

Reference yield:

: 35057-99-9
(E)-3-bromo-2-methylbut-2-enoic acid

: 1638136-91-0
(E)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

: 1638136-92-1
(Z)-(((2,2,4,5-tetramethylhexa-3,5-dien-1-yl)oxy)methanetriyl)tribenzene

Guidance literature:: Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / tetrahydrofuran

2: sodium sulfate / tetrahydrofuran

3: tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) / benzene / 80 °C / Inert atmosphere

With lithium aluminium tetrahydride; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; sodium sulfate; In tetrahydrofuran; benzene;
DOI:10.1002/anie.201403234