(4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

Base Information

Chemical Name:(4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone
CAS No.:182314-18-7
Molecular Formula:C₃₅H₄₄O₆
Molecular Weight:560.731
Hs Code.:

Synonyms:(4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

Suppliers and Price of (4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

There total 1 articles about (4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2-[3-((2S,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-1-methyl-1-nitro-heptylsulfanyl]-pyridine

: 182314-18-7
(4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

: (S)-4-((2S,4R,5S,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-octan-2-one

Guidance literature:: With ammonium hydroxide; titanium(III) chloride; In tetrahydrofuran; water; at 48 ℃; pH 5-6;
DOI:10.1021/jo961499b

Reference yield: 82.0%

: 108-98-5
thiophenol

: 182314-18-7
(4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

: 119070-22-3
phenyl 2-deoxy-3,4,6-tris-O-(phenylmethyl)-1-thio-D-arabino-hexopyranoside

: 65651-62-9
(4R)-4-hydroxy-2-octanone

: (4S)-4-hydroxy-2-octanone

Guidance literature:: With boron trifluoride diethyl etherate; In dichloromethane; -78 deg C -> room temperature;
DOI:10.1021/jo961499b

Reference yield:

: 182314-18-7
(4R)-4-[[2-deoxy-3,4,6-tris-O-(phenylmethyl)-α-D-arabino-hexopyranosyl]oxy]-2-octanone

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

Guidance literature:: Multi-step reaction with 3 steps

1: PhSH, BF₃*OEt₂ / CH₂Cl₂ / -78 deg C -> room temperature

2: Oxone / methanol; tetrahydrofuran; H₂O

3: benzene / Heating

With Oxone; boron trifluoride diethyl etherate; thiophenol; In tetrahydrofuran; methanol; dichloromethane; water; benzene;
DOI:10.1021/jo961499b