Technology Process of C26H41NO3SSi
There total 4 articles about C26H41NO3SSi which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
palladium diacetate; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine;
In
dichloromethane;
at 20 ℃;
for 13h;
optical yield given as %de;
diastereoselective reaction;
sealed tube;
Inert atmosphere;
DOI:10.1021/ja2116298
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: triethylamine / dichloromethane
2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: 26 h / 20 °C / Inert atmosphere
3.1: palladium diacetate; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine / dichloromethane / 13 h / 20 °C / sealed tube; Inert atmosphere
With
n-butyllithium; palladium diacetate; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja2116298
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere
1.2: 26 h / 20 °C / Inert atmosphere
2.1: palladium diacetate; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine / dichloromethane / 13 h / 20 °C / sealed tube; Inert atmosphere
With
n-butyllithium; palladium diacetate; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine;
In
tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja2116298
