tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol

Base Information

• Chemical Name: tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol
• CAS No.: 34020-54-7
• Molecular Formula: C₂₂H₂₄O₉
• Molecular Weight: 432.427
• Mol file: 34020-54-7.mol

Synonyms:tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol

Chemical Property of tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol

There total 1 articles about tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenylethynylmagnesium bromide (6738-06-3) + 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol (34020-54-7)

Guidance literature:

With diethyl ether; Behandeln des Reaktionsprodukts mit Acetanhydrid und Pyridin;

DOI:10.1021/jo01100a012

Reference yield: 76.0%

tetra-O-acetyl-1-phenyl-3,7-anhydro-1,2-dideoxy-D-gulo-oct-1-initol (34020-54-7) + 1-chloro-1,3-bis(2,4,6-trichlorophenyl)triazene (187464-05-7) → 5-Phenyl-4-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

Guidance literature:

With antimonypentachloride; In dichloromethane; at -60 - 0 ℃; for 2.5h;

upstream raw materials:

phenylethynylmagnesium bromide

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide