Silane, (1,1-dimethylethyl)dimethyl((2-(5-((tetrahydro-2H-pyran-2-yl)oxy)-3-pentenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

Base Information

Chemical Name:Silane, (1,1-dimethylethyl)dimethyl((2-(5-((tetrahydro-2H-pyran-2-yl)oxy)-3-pentenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-
CAS No.:101859-40-9
Molecular Formula:C22H42 O3 Si
Molecular Weight:382.6526
Hs Code.:

Synonyms:101859-40-9;Silane, (1,1-dimethylethyl)dimethyl((2-(5-((tetrahydro-2H-pyran-2-yl)oxy)-3-pentenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, (1,1-dimethylethyl)dimethyl((2-(5-((tetrahydro-2H-pyran-2-yl)oxy)-3-pentenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

Chemical Property:

Vapor Pressure:2.8E-07mmHg at 25°C
Boiling Point:432.5°C at 760 mmHg
Flash Point:177.6°C
Density:0.95g/cm³
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:9
Exact Mass:382.29032173
Heavy Atom Count:26
Complexity:428

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1CCCCC1CCC=CCOC2CCCCO2
Isomeric SMILES:CC(C)(C)[Si](C)(C)O[C@H]1CCCC[C@@H]1CC/C=C/COC2CCCCO2

Technology Process of Silane, (1,1-dimethylethyl)dimethyl((2-(5-((tetrahydro-2H-pyran-2-yl)oxy)-3-pentenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))-

There total 6 articles about Silane, (1,1-dimethylethyl)dimethyl((2-(5-((tetrahydro-2H-pyran-2-yl)oxy)-3-pentenyl)cyclohexyl)oxy)-, (1alpha,2beta(E))- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 110-87-2
3,4-dihydro-2H-pyran

: 101859-39-6,101976-95-8
(E)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclohexyl]-pent-2-en-1-ol

: 101859-40-9
tert-Butyl-dimethyl-{(1R,2S)-2-[(E)-5-(tetrahydro-pyran-2-yloxy)-pent-3-enyl]-cyclohexyloxy}-silane

Guidance literature:: With pyridinium p-toluenesulfonate; In dichloromethane;
DOI:10.1021/jo00362a014

Reference yield:

: 286-20-4
cyclohexane-1,2-epoxide

: 101859-40-9
tert-Butyl-dimethyl-{(1R,2S)-2-[(E)-5-(tetrahydro-pyran-2-yloxy)-pent-3-enyl]-cyclohexyloxy}-silane

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) CuI / 1.) Et₂O

2: 75 percent / TEA,DMAP / tetrahydrofuran; dimethylformamide / Heating

3: 1.) O₃, 2.) Me₂S / 1.) MeOH, - 60 deg C

4: CHCl₃ / Heating

5: dibal / diethyl ether / -78 - 0 °C

6: 93 percent / PPTS / CH₂Cl₂

With dmap; copper(l) iodide; dimethylsulfide; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; ozone; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1021/jo00362a014

Reference yield:

: 1773-36-0,3392-93-6,90974-59-7
trans-2-but-3-enylcyclohexanol

: 101859-40-9
tert-Butyl-dimethyl-{(1R,2S)-2-[(E)-5-(tetrahydro-pyran-2-yloxy)-pent-3-enyl]-cyclohexyloxy}-silane

Guidance literature:: Multi-step reaction with 5 steps

1: 75 percent / TEA,DMAP / tetrahydrofuran; dimethylformamide / Heating

2: 1.) O₃, 2.) Me₂S / 1.) MeOH, - 60 deg C

3: CHCl₃ / Heating

4: dibal / diethyl ether / -78 - 0 °C

5: 93 percent / PPTS / CH₂Cl₂

With dmap; dimethylsulfide; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; ozone; In tetrahydrofuran; diethyl ether; dichloromethane; chloroform; N,N-dimethyl-formamide;
DOI:10.1021/jo00362a014