methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

Base Information

Chemical Name:methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate
CAS No.:862498-72-4
Molecular Formula:C₂₁H₃₀N₂O₆
Molecular Weight:406.479
Hs Code.:

Synonyms:methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

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Chemical Property of methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

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Technology Process of methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

There total 5 articles about methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 78553-47-6
methyl (2S)-2-[N-(benzyloxycarbonyl)amino]pent-4-enoate

: 156731-40-7
tert-butyl N-but-3-enylcarbamate

: 862498-72-4
methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

Guidance literature:: Grubbs catalyst first generation; In dichloromethane; for 16h; Heating;
DOI:10.1016/j.tet.2005.05.021

Reference yield:

: 470443-12-0
di-tert-butyl N-3-butenyliminodicarboxylate

: 862498-72-4
methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / TFA / CH₂Cl₂ / 0.08 h / 20 °C

2: 69 percent / RuCl₂(PCy₃)2(=CHPh) / CH₂Cl₂ / 16 h / Heating

With trifluoroacetic acid; Grubbs catalyst first generation; In dichloromethane;
DOI:10.1016/j.tet.2005.05.021

Reference yield:

: 51779-32-9
iminodicarboxylic acid di-tert-butyl ester

: 862498-72-4
methyl (2S,4E/Z)-2-(benzyloxycarboxamido)-7-(tert-butoxycarboxamido)-4-heptenoate

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / cesium carbonate; lithium iodide / butan-2-one / 48 h / Heating

2: 96 percent / TFA / CH₂Cl₂ / 0.08 h / 20 °C

3: 69 percent / RuCl₂(PCy₃)2(=CHPh) / CH₂Cl₂ / 16 h / Heating

With caesium carbonate; trifluoroacetic acid; lithium iodide; Grubbs catalyst first generation; In dichloromethane; butanone;
DOI:10.1016/j.tet.2005.05.021