(E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

Base Information

Chemical Name:(E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester
CAS No.:76013-17-7
Molecular Formula:C₁₇H₂₄O₅S
Molecular Weight:340.441
Hs Code.:

Synonyms:(E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

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Chemical Property of (E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

Chemical Property:

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Technology Process of (E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

There total 2 articles about (E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 60729-65-9
methyl phenylsulfonylacetate sodium salt

: 75646-37-6
Acetic acid (Z)-4-hydroxy-1,1,4-trimethyl-pent-2-enyl ester

: 76013-17-7
(E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; at 60 ℃; for 15h;
DOI:10.1016/S0040-4039(00)77440-5

Reference yield:

: 6117-86-8
(Z)-2,5-dimethylhex-3-ene-2,5-diol

: 76013-17-7
(E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 75 percent / diethylamine / 4-Dimethylamino pyridine / CH₂Cl₂ / 3 h

2: 85 percent / Tetrakis (triphenylphosphine) palladium / 15 h / 60 °C

With diethylamine; dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In dichloromethane;
DOI:10.1016/S0040-4039(00)77440-5

Reference yield:

: 76013-17-7
(E)-2-Benzenesulfonyl-6-hydroxy-3,3,6-trimethyl-hept-4-enoic acid methyl ester

: 827-90-7,2259-14-5,2935-23-1,4638-92-0,10453-89-1,15259-78-6,26771-06-2,26771-11-9,705-16-8
trans-chrysanthemic acid

Guidance literature:: Multi-step reaction with 3 steps

2: 1.) NaH 2.) Na/Hg, NaHPO₄ / 1.) THF, 65 deg C, 15 h 2.) ethanol. Product ratio cis and trans = 1:1

3: H₂O / hydrolisis and isomerization

With sodium amalgam; camphor-10-sulfonic acid; water; sodium hydride;
DOI:10.1016/S0040-4039(00)77440-5