(3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

Base Information

Chemical Name:(3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane
CAS No.:796843-82-8
Molecular Formula:C₃₃H₅₈O₃Si
Molecular Weight:530.907
Hs Code.:

Synonyms:(3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

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Chemical Property of (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

Chemical Property:

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Technology Process of (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

There total 7 articles about (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 796843-79-3
(3S,4S)-4-(benzyloxy)dodec-1-en-3-ol

: 796843-81-7
tert-butyl(1R)-1-(5-{[tert-butyldimethylsilyl]oxy}pentyl)prop-2-en-1-yl carbonate

: [(R)-6-((1R,2S)-2-Benzyloxy-1-vinyl-decyloxy)-oct-7-enyloxy]-tert-butyl-dimethyl-silane

: 796843-82-8
(3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

Guidance literature:: With copper(l) iodide; lithium bis(trimethylamide); phosphorous acid trimethyl ester; tris(triphenylphosphine)rhodium(I) chloride; In tetrahydrofuran; at 0 - 20 ℃; for 18h;
DOI:10.1002/anie.200460612

Reference yield:

: 796843-80-6
(3R)-8-{[(tert-butyl)(dimethyl)silyl]oxy}oct-1-en-3-ol

: 796843-82-8
(3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / lithium bis(trimethylsilyl)amide / tetrahydrofuran / 12 h / 0 °C

2: trimethyl phosphite; lithium bis(trimethylamide); copper(I) iodide / [RhCl(PPh₃)3] / tetrahydrofuran / 18 h / 0 - 20 °C

With copper(l) iodide; lithium bis(trimethylamide); lithium hexamethyldisilazane; phosphorous acid trimethyl ester; tris(triphenylphosphine)rhodium(I) chloride; In tetrahydrofuran;
DOI:10.1002/anie.200460612

Reference yield:

: 796843-78-2
(3S,4S)-3-3(4-methoxyphenoxy)dodec-1-en-4-ol

: 796843-82-8
(3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / dimethylformamide; tetrahydrofuran / 0 - 20 °C

2: 77 percent / ceric ammonium nitrate / acetonitrile; H₂O / 3 h / 20 °C

3: trimethyl phosphite; lithium bis(trimethylamide); copper(I) iodide / [RhCl(PPh₃)3] / tetrahydrofuran / 18 h / 0 - 20 °C

With copper(l) iodide; ammonium cerium(IV) nitrate; lithium bis(trimethylamide); sodium hydride; phosphorous acid trimethyl ester; tris(triphenylphosphine)rhodium(I) chloride; In tetrahydrofuran; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1002/anie.200460612