Technology Process of (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane
There total 7 articles about (3S,4S,6R)-13,13,14,14-tetramethyl-3-octyl-1-phenyl-4,6-divinyl-2,5,12-trioxa-13-silapentadecane which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
copper(l) iodide; lithium bis(trimethylamide); phosphorous acid trimethyl ester;
tris(triphenylphosphine)rhodium(I) chloride;
In
tetrahydrofuran;
at 0 - 20 ℃;
for 18h;
DOI:10.1002/anie.200460612
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 82 percent / lithium bis(trimethylsilyl)amide / tetrahydrofuran / 12 h / 0 °C
2: trimethyl phosphite; lithium bis(trimethylamide); copper(I) iodide / [RhCl(PPh3)3] / tetrahydrofuran / 18 h / 0 - 20 °C
With
copper(l) iodide; lithium bis(trimethylamide); lithium hexamethyldisilazane; phosphorous acid trimethyl ester;
tris(triphenylphosphine)rhodium(I) chloride;
In
tetrahydrofuran;
DOI:10.1002/anie.200460612
- Guidance literature:
-
Multi-step reaction with 3 steps
1: sodium hydride / dimethylformamide; tetrahydrofuran / 0 - 20 °C
2: 77 percent / ceric ammonium nitrate / acetonitrile; H2O / 3 h / 20 °C
3: trimethyl phosphite; lithium bis(trimethylamide); copper(I) iodide / [RhCl(PPh3)3] / tetrahydrofuran / 18 h / 0 - 20 °C
With
copper(l) iodide; ammonium cerium(IV) nitrate; lithium bis(trimethylamide); sodium hydride; phosphorous acid trimethyl ester;
tris(triphenylphosphine)rhodium(I) chloride;
In
tetrahydrofuran; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1002/anie.200460612
