trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane

Base Information

Chemical Name:trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane
CAS No.:1393650-37-7
Molecular Formula:C₁₁H₁₄O₃
Molecular Weight:194.23
Hs Code.:

Synonyms:trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane

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Technology Process of trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane

There total 2 articles about trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4407-36-7
(2E)-3-phenyl-2-propen-1-ol

: (2S,3S)-2,3-epoxy-O-methoxymethyl-3-phenyl-propan-1-ol

: 1393650-37-7
trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane

Guidance literature:: Multi-step reaction with 2 steps

1: dmap; N-ethyl-N,N-diisopropylamine / dichloromethane / 15 h / 0 - 20 °C

2: N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene silver chloride; C₄₂H₃₀Cl₂FeN₃O₂; iodosylbenzene; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate / dichloromethane / 1 h / 0 °C

With dmap; N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene silver chloride; iodosylbenzene; C₄₂H₃₀Cl₂FeN₃O₂; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; N-ethyl-N,N-diisopropylamine; In dichloromethane;
DOI:10.1021/ja304219s

Reference yield:

: 91970-13-7
1-((E)-3-(methoxymethoxy)prop-1-enyl)benzene

: (2S,3S)-2,3-epoxy-O-methoxymethyl-3-phenyl-propan-1-ol

: 1393650-37-7
trans-(2R,3R)-2-(methoxymethoxy)methyl-3-phenyloxirane

Guidance literature:: With N,N'-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene silver chloride; iodosylbenzene; C₄₂H₃₀Cl₂FeN₃O₂; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; In dichloromethane; at 0 ℃; for 1h; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ja304219s