(2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical

Base Information

Chemical Name:(2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical
CAS No.:85591-99-7
Molecular Formula:C₉H₁₃BrNO₂
Molecular Weight:247.112
Hs Code.:
DSSTox Substance ID:DTXSID901165042
Mol file:85591-99-7.mol

Synonyms:(2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical

Suppliers and Price of (2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Medical Isotopes, Inc.
3-Bromo-4-formyl-2,5-dihydro-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxy
100 mg
$ 2400.00

Medical Isotopes, Inc.
3-Bromo-4-formyl-2,5-dihydro-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxy
10 mg
$ 675.00

Total 3 raw suppliers

Chemical Property of (2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical

Chemical Property:

Storage Temp.:-20°C Freezer, Under inert atmosphere
Solubility.:Chloroform, DCM
XLogP3:0.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:247.02079
Heavy Atom Count:13
Complexity:281

Purity/Quality:: 3-Bromo-4-formyl-2,5-dihydro-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxy ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C(=C(C(N1O)(C)C)Br)C=O)C
Uses 3-Bromo-4-formyl-2,5-dihydro-2,2,5,5-tetramethyl-1H-pyrrol-1-yloxy is an intermediate in the synthesis of highly active spin labelling reagents.

Technology Process of (2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical

There total 5 articles about (2,2,5,5-Tetramethyl-3-bromo-4-formyl-3-pyrroline-1-yloxy)radical which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 85591-93-1
3-bromo-4-hydroxymethyl-2,2,5,5-tetramethyl-Δ³-pyrrolin-1-oxyl

: 85591-99-7
3-bromo-4-formyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxyl radical

Guidance literature:: With pyridine; chromium(VI) oxide; In dichloromethane; for 0.25h;
DOI:10.1007/BF00957952

Reference yield: 81.0%

: 85065-49-2
1-oxyl-3-bromo-2,2,5,5-tetramethyl-Δ³-pyrrolin-4-carboxylic acid chloride

: 85591-99-7
3-bromo-4-formyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxyl radical

Guidance literature:: With cadmium tetrahydroborate; N,N,N,N,N,N-hexamethylphosphoric triamide; In acetonitrile; for 0.666667h;
DOI:10.1007/BF00957952

Reference yield:

: 85466-58-6
1-oxyl-3-bromo-2,2,5,5-tetramethyl-Δ³-pyrrolin-4-carboxylic acid and methoxycarbonic acid mixed anhydride

: 85591-99-7
3-bromo-4-formyl-2,2,5,5-tetramethyl-2,5-dihydro-1H-pyrrol-1-yloxyl radical

Guidance literature:: Multi-step reaction with 2 steps

1: 75.2 percent / NaBH₄ / ethanol / 2 h

2: 90 percent / CrO₃, pyridine / CH₂Cl₂ / 0.25 h

With pyridine; chromium(VI) oxide; sodium tetrahydroborate; In ethanol; dichloromethane;
DOI:10.1007/BF00957952