thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

Base Information

Chemical Name:thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester
CAS No.:876310-89-3
Molecular Formula:C₂₀H₃₅N₂O₁₂PS
Molecular Weight:558.544
Hs Code.:

thiophosphoric acid <i>O</i>,<i>O</i>'-bis-(2-cyano-ethyl) ester <i>O</i>''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

Synonyms:thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

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Chemical Property of thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

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Technology Process of thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

There total 2 articles about thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: thiophosphoric acid O-[3-(tert-butyl-diphenyl-silanyloxy)-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl] ester O',O''-bis-(2-cyano-ethyl) ester

: 876310-89-3
thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

Guidance literature:: With pyridine hydrogenfluoride; In tetrahydrofuran; at 20 ℃; for 504000h;
DOI:10.1021/ja0554716

Reference yield:

: 102690-88-0
bis(2-cyanoethyl) diisopropylamidophosphite

: 876310-89-3
thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-tetrazole / acetonitrile / 2 h / 20 °C

1.2: 91 percent / sulfur; pyridine / acetonitrile; CS₂ / 2 h / 20 °C

2.1: 86 percent / pyridine*HF / tetrahydrofuran / 504000 h / 20 °C

With 1H-tetrazole; pyridine hydrogenfluoride; In tetrahydrofuran; acetonitrile;
DOI:10.1021/ja0554716

Reference yield: 86.0%

: 876310-81-5
N,N-diisopropyl-O-cyanoethyl-O-(di-butanoyl-sn-(2S)-glycerol)phosphonamidite

: 876310-89-3
thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester

: 876310-84-8
Butyric acid (R)-2-[{(1S,2S,3R,4S,5R,6R)-3-[bis-(2-cyano-ethoxy)-thiophosphoryloxy]-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyloxy}-(2-cyano-ethoxy)-phosphoryloxy]-1-butyryloxymethyl-ethyl ester

Guidance literature:: N,N-diisopropyl-O-cyanoethyl-O-(di-butanoyl-sn-(2S)-glycerol)phosphonamidite; thiophosphoric acid O,O'-bis-(2-cyano-ethyl) ester O''-(3-hydroxy-2,4,5,6-tetrakis-methoxymethoxy-cyclohexyl) ester; With 1H-tetrazole; In tetrahydrofuran; at 20 ℃; for 16h;

With tert.-butylhydroperoxide; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1021/ja0554716