2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid

Base Information

• Chemical Name: 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid
• CAS No.: 101981-34-4
• Molecular Formula: C₆₁H₆₃ClO₁₀
• Molecular Weight: 1005.51
• Mol file: 101981-34-4.mol

Synonyms:2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid

Chemical Property of 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid

There total 1 articles about 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(2-Methoxyethyl)-2,3,6-tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-β-D-glucopyranosid (101981-33-3) → 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid (101981-34-4)

Guidance literature:

With titanium tetrachloride;

DOI:10.1016/S0040-4039(00)95120-7

Reference yield: 54.0%

Acetic acid (2R,3S,4R,5S,6S)-3-acetoxy-6-((2S,3R,4R,5R,6R)-5-acetoxy-6-benzyloxy-4-hydroxy-2-methyl-tetrahydro-pyran-3-yloxy)-2-acetoxymethyl-5-azido-tetrahydro-pyran-4-yl ester (101981-22-0) + 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid (101981-34-4) → C88H83(2)H14N3O23 + C88H83(2)H14N3O23

Guidance literature:

With silver trifluoromethanesulfonate; tetramethylurea; In dichloromethane;

DOI:10.1016/S0040-4039(00)95120-7

Reference yield: 48.0%

9-[(4aR,6R,7S,8R,8aS)-7-Azido-8-((2S,3R,4R,5R,6S)-3,5-diacetoxy-4-hydroxy-6-methyl-tetrahydro-pyran-2-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy]-nonanoic acid methyl ester + 2,3,6-Tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-α-D-glucopyranosylchlorid (101981-34-4) → C94H95(2)H14N3O23 + C94H95(2)H14N3O23

Guidance literature:

With mercury(II) cyanide; mercury dibromide; In dichloromethane;

DOI:10.1016/S0040-4039(00)95120-7

upstream raw materials:

(2-Methoxyethyl)-2,3,6-tri-O-<α,α-D2>benzyl-4-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-β-D-glucopyranosid

Downstream raw materials:

Benzyl-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-(1->4)-O-(2,3,6-tri-O-<α,α-D2>benzyl-β-D-glucopyranosyl)-(1->3)-O-<(3,4,6-tri-O-acetyl-2-azido-2-desoxy-β-D-mannopyranosyl)-(1->4)>-2-O-acetyl-α-L-rhamnopyranosid

Benzyl-O-(2,3,4,6-tetra-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-(1->4)-O-(2,3,6-tri-O-<α,α-D2>benzyl-α-D-glucopyranosyl)-(1->3)-O-<(3,4,6-tri-O-acetyl-2-azido-2-desoxy-β-D-mannopyranosyl)-(1->4)>-2-O-acetyl-α-L-rhamnopyranosid