[(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

Base Information

Chemical Name:[(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene
CAS No.:475232-64-5
Molecular Formula:C₂₁H₂₉BrS
Molecular Weight:393.431
Hs Code.:

Synonyms:[(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

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Chemical Property of [(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

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Technology Process of [(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

There total 1 articles about [(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 242485-40-1
4-benzenesulfinyl-3-methyl-5-(2,3,3-trimethyl-cyclohex-1-enyl)-pent-1-en-3-ol

: 475232-64-5
[(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

Guidance literature:: With pyridine; phosphorus tribromide; In diethyl ether; at -35 ℃; for 2h;
DOI:10.1016/S0040-4020(02)00752-4

Reference yield:

: 33840-74-3
1-(phenylsulfinyl)propan-2-one

: 475232-64-5
[(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

: 475287-97-9
(E)-3-Benzenesulfinyl-6-methyl-7-phenylsulfanyl-8-(2,3,3-trimethyl-cyclohex-1-enyl)-oct-5-en-2-one

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 20 ℃; for 12h;
DOI:10.1016/S0040-4020(02)00752-4

Reference yield:

: 475232-64-5
[(E)-4-Bromo-2-methyl-1-(2,3,3-trimethyl-cyclohex-1-enylmethyl)-but-2-enylsulfanyl]-benzene

: (3E,5E,7E)-[6-methyl-8-(2',3',3'-trimethylcyclohex-1'-enyl)-octa-3,5,7-trien-2-one]

Guidance literature:: Multi-step reaction with 4 steps

1: NaH / tetrahydrofuran / 12 h / 20 °C

2: 309 mg / CHCl₃ / 3 h / 50 °C

3: mCPBA / CH₂Cl₂ / 3 h / -78 °C

4: 127 mg / CHCl₃ / 5 h / 60 °C

With sodium hydride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1016/S0040-4020(02)00752-4