anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid

Base Information

• Chemical Name: anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid
• CAS No.: 81268-07-7
• Molecular Formula: C₁₆H₁₅N₃O₂
• Molecular Weight: 281.314
• Mol file: 81268-07-7.mol

Synonyms:anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid

Chemical Property of anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid

There total 1 articles about anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-Phenyl-1,2,4-triazolidine-3,5-dione (4233-33-4) + 7-methyl-1,3,5-cycloheptatriene (4281-04-3) → anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.02,4>non-8-en-6,7-dicarbonsaeure-phenylimid (81268-07-7)

Guidance literature:

In diethyl ether; acetone; at 0 ℃;

Reference yield: 92.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.02,4>non-8-en-6,7-dicarbonsaeure-phenylimid (81268-07-7) → anti-9-Methyl-3,4,11,12-tetraza-exo,endo-tetracyclo<5.3.2.02,6.08,10>dodec-3-en-11,12-dicarbonsaeure-phenylimid (81268-10-2)

Guidance literature:

In diethyl ether; N,N-dimethyl-formamide;

Reference yield: 78.0%

Diazoethan (1117-96-0) + anti-3-Methyl-6,7-diaza-exo-tricyclo<3.2.2.02,4>non-8-en-6,7-dicarbonsaeure-phenylimid (81268-07-7) → 5-anti-9-dimethyl-3,4,11,12-tetraza-exo,endo-tetracyclo<5.3.2.02,6.08,10>dodec-3-ene-11,12-dicarboxylic acid phenylimide (90857-50-4)

Guidance literature:

In diethyl ether; N,N-dimethyl-formamide; several days in the dark;

DOI:10.1016/S0040-4020(01)91187-1

upstream raw materials:

4-Phenyl-1,2,4-triazolidine-3,5-dione

7-methyl-1,3,5-cycloheptatriene

Downstream raw materials:

anti-9-Methyl-3,4,11,12-tetraza-exo,endo-tetracyclo<5.3.2.0^2,6.0^8,10>dodec-3-en-11,12-dicarbonsaeure-phenylimid

5-anti-9-dimethyl-3,4,11,12-tetraza-exo,endo-tetracyclo<5.3.2.0^2,6.0^8,10>dodec-3-ene-11,12-dicarboxylic acid phenylimide

5,5,anti-9-trimethyl-3,4,11,12-tetraza-exo,endo-tetracyclo<5.3.2.0^2,6.0^8,10>dodec-3-ene-11,12-dicarboxylic acid phenylimide

anti-3,8-Dimethyl-6,7-diaza-exo-tricyclo<3.2.2.0^2,4>non-8-en-6,7-dicarbonsaeure-phenylimid