Technology Process of C15H9BrF2N2O
There total 6 articles about C15H9BrF2N2O which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C16H8BrF2NO3;
With
diphenyl phosphoryl azide; triethylamine;
In
tert-butyl alcohol;
at 85 ℃;
for 5h;
With
trifluoroacetic acid;
In
ethanol;
at 20 ℃;
for 17.5h;
DOI:10.1055/s-0031-1290079
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / tetrahydrofuran; water; tert-butyl alcohol / 3 h / 20 °C
2.1: diphenyl phosphoryl azide; triethylamine / tert-butyl alcohol / 5 h / 85 °C
2.2: 17.5 h / 20 °C
With
sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; diphenyl phosphoryl azide; triethylamine;
In
tetrahydrofuran; water; tert-butyl alcohol;
1.1: Pinnick oxidation / 2.1: Curtius rearrangement;
DOI:10.1055/s-0031-1290079
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: potassium carbonate / dimethyl sulfoxide / 1 h / 90 °C
2.1: selenium(IV) oxide / 1,4-dioxane / 4 h / Reflux
3.1: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / tetrahydrofuran; water; tert-butyl alcohol / 3 h / 20 °C
4.1: diphenyl phosphoryl azide; triethylamine / tert-butyl alcohol / 5 h / 85 °C
4.2: 17.5 h / 20 °C
With
selenium(IV) oxide; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; diphenyl phosphoryl azide; potassium carbonate; triethylamine;
In
tetrahydrofuran; 1,4-dioxane; water; dimethyl sulfoxide; tert-butyl alcohol;
3.1: Pinnick oxidation / 4.1: Curtius rearrangement;
DOI:10.1055/s-0031-1290079
