1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

Base Information

Chemical Name:1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane
CAS No.:879687-56-6
Molecular Formula:C₂₂H₂₂F₉IO₉S₃
Molecular Weight:824.499
Hs Code.:

Synonyms:1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

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Chemical Property of 1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

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Technology Process of 1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

There total 4 articles about 1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 879687-54-4
1-phenyl-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

: 879687-56-6
1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

: trifluoro-methanesulfonic acid 3-(2,4-diiodo-phenyl)-5,7-bis-trifluoromethanesulfonyloxymethyl-adamantan-1-ylmethyl ester

Guidance literature:: With iodine; bis-[(trifluoroacetoxy)iodo]benzene; In tetrachloromethane; at 20 ℃; for 4h;
DOI:10.1021/jo051863j

Reference yield:

: 879687-46-4
1-bromo-3,5,7-tris(hydroxymethyl)adamantane

: 879687-56-6
1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

Guidance literature:: Multi-step reaction with 3 steps

1: 88 percent / pyridine / CH₂Cl₂ / 2 h / 0 °C

2: 83 percent / AgSbF₆ / CH₂Cl₂ / 90 h / Heating

3: 56 percent / PhI(OCOCF₃)2; I₂ / CCl₄ / 4 h / 20 °C

With pyridine; silver hexafluoroantimonate; iodine; bis-[(trifluoroacetoxy)iodo]benzene; In tetrachloromethane; dichloromethane;
DOI:10.1021/jo051863j

Reference yield:

: 879687-44-2
1-bromo-3,5,7-tris(methoxycarbonyl)adamantane

: 879687-56-6
1-(4-iodophenyl)-3,5,7-tris[(trifluoromethylsulfonyloxy)methyl]adamantane

Guidance literature:: Multi-step reaction with 4 steps

1: 95 percent / lithium aluminum hydride / diethyl ether / 3.5 h / 20 °C

2: 88 percent / pyridine / CH₂Cl₂ / 2 h / 0 °C

3: 83 percent / AgSbF₆ / CH₂Cl₂ / 90 h / Heating

4: 56 percent / PhI(OCOCF₃)2; I₂ / CCl₄ / 4 h / 20 °C

With pyridine; silver hexafluoroantimonate; lithium aluminium tetrahydride; iodine; bis-[(trifluoroacetoxy)iodo]benzene; In tetrachloromethane; diethyl ether; dichloromethane;
DOI:10.1021/jo051863j