1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Base Information

Chemical Name:1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane
CAS No.:307930-91-2
Molecular Formula:C₂₇H₂₁F₅N₂OSi
Molecular Weight:512.554
Hs Code.:

Synonyms:1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Suppliers and Price of 1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

There total 3 articles about 1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 167482-91-9
5-(pentafluorophenyl)dipyrromethane

: 262267-34-5
S-2-pyridyl 4-[2-(trimethylsilyl)ethynyl]benzothioate

: 307930-91-2
1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Guidance literature:: 5-(pentafluorophenyl)dipyrromethane; With ethylmagnesium bromide; In tetrahydrofuran; at 20 ℃; for 0.166667h;

S-2-pyridyl 4-[2-(trimethylsilyl)ethynyl]benzothioate; In tetrahydrofuran; for 0.5h; Further stages.;
DOI:10.1021/jo000882k

Reference yield:

: 262267-33-4
S-(2-pyridyl) 4-iodothiobenzoate

: 307930-91-2
1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 70 percent / CuI; Et₃N; Ph₃P / Pd₂(dba)3 / tetrahydrofuran / 13 h / 20 - 50 °C

2.1: EtMgBr / tetrahydrofuran / 0.17 h / 20 °C

2.2: 62 percent / tetrahydrofuran / 0.5 h

With copper(l) iodide; ethylmagnesium bromide; triethylamine; triphenylphosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; 1.1: coupling / 2.1: Metallation / 2.2: Acylation;
DOI:10.1021/jo000882k

Reference yield:

: 1066-54-2
trimethylsilylacetylene

: 307930-91-2
1-{4-[2-(trimethylsilyl)ethynyl]benzoyl}-5-(pentafluorophenyl)dipyrromethane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 70 percent / CuI; Et₃N; Ph₃P / Pd₂(dba)3 / tetrahydrofuran / 13 h / 20 - 50 °C

2.1: EtMgBr / tetrahydrofuran / 0.17 h / 20 °C

2.2: 62 percent / tetrahydrofuran / 0.5 h

With copper(l) iodide; ethylmagnesium bromide; triethylamine; triphenylphosphine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; 1.1: coupling / 2.1: Metallation / 2.2: Acylation;
DOI:10.1021/jo000882k