(+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane

Base Information

• Chemical Name: (+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane
• CAS No.: 103668-54-8
• Molecular Formula: C₁₅H₂₄O₂Si
• Molecular Weight: 264.44

Synonyms:(+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane

Chemical Property of (+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane

Chemical Property:

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Technology Process of (+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane

There total 1 articles about (+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(E)-(R)-4-Benzyloxy-2-methyl-pent-3-en-1-ol + 1,1,3,3-tetramethyldisilazane (15933-59-2) → (+/-)-2,2,4-trimethyl-3-(2-benzyloxy-1-methyletyl)-1-oxa-2-silacyclopentane (103668-54-8)

Guidance literature:

dihydrogen hexachloroplatinate; Yield given. Multistep reaction; 2) 60 deg C, 3 h;

DOI:10.1021/ja00279a097

Reference yield: 95.0%

(3S,4R)-3-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,4-trimethyl-[1,2]oxasilolane (103668-54-8,103729-89-1) → (2S,4R)-5-(benzyloxy)-2,4-dimethylpentan-1-ol (157810-31-6)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 25 ℃;

DOI:10.1021/jo00032a007

Reference yield: 77.0%

(3S,4R)-3-((R)-2-Benzyloxy-1-methyl-ethyl)-2,2,4-trimethyl-[1,2]oxasilolane (103668-54-8,103729-89-1) → (2S,4S)-5-benzyloxy-2,4-dimethyl-pentan-1-ol (169105-68-4)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 25 ℃;

DOI:10.1021/jo00032a007

upstream raw materials:

1,1,3,3-tetramethyldisilazane

Downstream raw materials:

(2S,4S)-5-benzyloxy-2,4-dimethyl-pentan-1-ol

(2S,4R)-5-(benzyloxy)-2,4-dimethylpentan-1-ol

(2S,3R,4R,6S)-3-Hydroxy-2-methoxy-4,6-dimethyl-7-trityloxy-heptanoic acid methoxy-methyl-amide

(S)-2-Hydroxy-N-methoxy-N-methyl-2-[(3R,4S,5R)-2,2,4-trimethyl-3-((R)-1-methyl-2-trityloxy-ethyl)-[1,2]oxasilolan-5-yl]-acetamide

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