3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

Base Information

Chemical Name:3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate
CAS No.:1620838-64-3
Molecular Formula:C₄₃H₄₅NO₁₇S
Molecular Weight:879.893
Hs Code.:

Synonyms:3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

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Chemical Property of 3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

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Technology Process of 3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

There total 4 articles about 3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 1000006-68-7
4TCNA

: 3947-62-4,10343-06-3,19235-21-3,22554-70-7,22860-22-6,47339-09-3,57884-82-9,62057-79-8,70191-05-8,109525-54-4,140147-37-1,6207-76-7
2,3,4,6-tetraacetylglucose

: 1620838-64-3
3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at -78 - 20 ℃; for 24h; Inert atmosphere;
DOI:10.1016/j.ejmech.2014.06.067

Reference yield:

: 98-59-9
p-toluenesulfonyl chloride

: 1620838-64-3
3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine / 2.5 h / 0 °C

2: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 24 h / -78 - 20 °C / Inert atmosphere

With pyridine; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; 2: |Mitsunobu Displacement;
DOI:10.1016/j.ejmech.2014.06.067

Reference yield:

: 1476-53-5,6990-02-9,18656-99-0
sodium novobiocin

: 1620838-64-3
3-(2,2-dimethylchroman-6-carboxamido)-7-(2,3,4,6-tetra-O-acetyl-β-glucopyranos-1-yl)-8-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 3 steps

1: ethanol / 1 h / Reflux

2: pyridine / 2.5 h / 0 °C

3: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 24 h / -78 - 20 °C / Inert atmosphere

With pyridine; di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; ethanol; 3: |Mitsunobu Displacement;
DOI:10.1016/j.ejmech.2014.06.067