(5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne

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Chemical Name:(5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne
CAS No.:402505-11-7
Molecular Formula:C₁₀₁H₁₀₆N₈O₈SiZn₂
Molecular Weight:1718.87
Hs Code.:

Synonyms:(5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne

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Chemical Property of (5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne

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Technology Process of (5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne

There total 1 articles about (5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 402505-25-3
(5-bromo-10,20-bis[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)

: 402505-09-3
(5-ethynyl-15-triisopropylsilylethynyl-10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)

: 402505-11-7
(5-triisopropylsilylethynyl-15,15'-bis[(10,20-di[4-(3-methoxy-3-methylbutoxy)phenyl]porphinato)zinc(II)])ethyne

Guidance literature:: With AsPh₃; triethyl amine; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; under N2, standard Schlenk techniques; THF and Et3N added to mixt. of Br-contg. Zn porphyrin, acetylene substituted Zn porphyrin, Pd2(dba)3 and AsPh3 (molar ratio 1.1:1:0.16:1.3); stirred (40°C, 4 h); volatiles evapd.; purified by chromy. (silica gel, hexanes-THF); dark green-brown band collected; purified by size-exclusion chromy. (SX-1 biobeads, THF);
DOI:10.1021/ic010871p