N,N'-m-phenylene-di-carbamonitrile

Base Information

• Chemical Name: N,N'-m-phenylene-di-carbamonitrile
• CAS No.: 13463-91-7
• Molecular Formula: C₈H₆N₄
• Molecular Weight: 158.162
• Mol file: 13463-91-7.mol

Synonyms:N,N'-m-phenylene-di-carbamonitrile

Chemical Property of N,N'-m-phenylene-di-carbamonitrile

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-m-phenylene-di-carbamonitrile

There total 10 articles about N,N'-m-phenylene-di-carbamonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

1,3-phenylene-bis-(1H)-tetrazole (125620-14-6) → N,N'-m-phenylene-di-carbamonitrile (13463-91-7)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; isopropyl alcohol; at 75 - 80 ℃; for 2.5h;

DOI:10.1007/BF00476984

Reference yield:

3-(tetrazol-1-yl)phenylamine (14213-12-8) → N,N'-m-phenylene-di-carbamonitrile (13463-91-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium azide / acetic acid / 3.5 h / 95 - 100 °C

2: 82 percent / KOH / dimethylsulfoxide; propan-2-ol / 2.5 h / 75 - 80 °C

With potassium hydroxide; sodium azide; In acetic acid; dimethyl sulfoxide; isopropyl alcohol;

DOI:10.1007/BF00476984

Reference yield:

1-(3-nitrophenyl)-1H-1,2,3,4-tetrazole (14213-10-6) → N,N'-m-phenylene-di-carbamonitrile (13463-91-7)

Guidance literature:

Multi-step reaction with 3 steps

1: SnCl₂ / aq. HCl

2: sodium azide / acetic acid / 3.5 h / 95 - 100 °C

3: 82 percent / KOH / dimethylsulfoxide; propan-2-ol / 2.5 h / 75 - 80 °C

With potassium hydroxide; sodium azide; tin(ll) chloride; In hydrogenchloride; acetic acid; dimethyl sulfoxide; isopropyl alcohol;

DOI:10.1007/BF00476984

upstream raw materials:

1,3-phenylenebisthiourea

bromocyane

m-phenylenediamine

1,3-phenylene-bis-(1H)-tetrazole

Downstream raw materials:

N,N''-m-phenylene-di-urea