(1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

Base Information

Chemical Name:(1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane
CAS No.:671796-16-0
Molecular Formula:C₂₉H₄₉NO₈
Molecular Weight:539.71
Hs Code.:

Synonyms:(1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

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Chemical Property of (1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

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Technology Process of (1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

There total 4 articles about (1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 492447-17-3,1185098-51-4
(4S,5S)-2-tert-butyl-4,5-dihydroxymethyl-2-methyldioxolane

: 333794-17-5
9-benzyl-1,17-diiodo-3,6,12,15-tetraoxa-9-azaheptadecane

: 671796-16-0
(1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

: 671796-17-1
(1S,23S,27S,49S)-12,38-dibenzyl-25,51-di-(tert-butyl)-25,51-dimethyl-3,6,9,15,18,21,24,26,29,32,35,41,44,47,50,52-hexadecaoxa-12,38-diazatricyclo[47.3.0.0^23,27]-dopentacontane

Guidance literature:: (4S,5S)-2-tert-butyl-4,5-dihydroxymethyl-2-methyldioxolane; With sodium hydride; In 1,4-dioxane; at 50 - 60 ℃; for 1h;

9-benzyl-1,17-diiodo-3,6,12,15-tetraoxa-9-azaheptadecane; at 70 - 80 ℃; for 16h;
DOI:10.1023/B:RUJO.0000003200.41968.46

Reference yield:

: 112-26-5,27252-69-3
1,2-bis(2-chloroethoxy)ethane

: 671796-16-0
(1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 67 percent / sodium carbonate / 8 h / 120 °C

2.1: 97 percent / sodium iodide / acetonitrile / 14 h / Heating

3.1: sodium hydride / dioxane / 1 h / 50 - 60 °C

3.2: 52 percent / 16 h / 70 - 80 °C

With sodium hydride; sodium carbonate; sodium iodide; In 1,4-dioxane; acetonitrile;
DOI:10.1023/B:RUJO.0000003200.41968.46

Reference yield:

: 100-46-9
benzylamine

: 671796-16-0
(1S,23S)-12-benzyl-25-(tert-butyl)-25-methyl-3,6,9,15,18,21,24,26-octaoxa-12-azabicyclo[21.3.0]-hexacosane

Guidance literature:: Multi-step reaction with 3 steps

1.1: 67 percent / sodium carbonate / 8 h / 120 °C

2.1: 97 percent / sodium iodide / acetonitrile / 14 h / Heating

3.1: sodium hydride / dioxane / 1 h / 50 - 60 °C

3.2: 52 percent / 16 h / 70 - 80 °C

With sodium hydride; sodium carbonate; sodium iodide; In 1,4-dioxane; acetonitrile;
DOI:10.1023/B:RUJO.0000003200.41968.46