1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose

Base Information

• Chemical Name: 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose
• CAS No.: 1206717-71-6
• Molecular Formula: C₁₃H₁₅NO₄S
• Molecular Weight: 281.332
• Mol file: 1206717-71-6.mol

Synonyms:1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose

Chemical Property of 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose

There total 10 articles about 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

1,6-anhydro-2,3,4-trideoxy-2,3-(tosylepimino)-β-D-ribo-hexopyranose (1206717-69-2) → 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose (1206717-71-6)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 18h;

DOI:10.1002/ejoc.200900762

Reference yield:

1,6-anhydro-2,3,4-trideoxy-2,3-(tosylepimino)-β-D-ribo-hexopyranose (1206717-69-2) → 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose (1206717-71-6) + 1,6-anhydro-3-bromo-2,3,4-trideoxy-2-(tosylamino)-β-D-ribo-hexopyranose (1206717-79-4) + 1,6-anhydro-3-bromo-2,3,4-trideoxy-2-(tosylamino)-β-D-xylo-hexopyranose (1206717-73-8)

Guidance literature:

With tetrabutylammomium bromide; ammonium bromide; In toluene; for 4h; Reflux;

DOI:10.1002/ejoc.200900762

Reference yield:

1,6-anhydro-2,3,4-trideoxy-2,3-(tosylepimino)-β-D-ribo-hexopyranose (1206717-69-2) → 1,6-anhydro-2,3,4-trideoxy-2-(tosylamino)-β-D-erythro-hex-2-enopyranose (1206717-71-6) + 1,6-anhydro-3-iodo-2,3,4-trideoxy-2-(tosylamino)-β-D-ribo-hexopyranose (1206717-81-8) + 1,6-anhydro-3-iodo-2,3,4-trideoxy-2-(tosylamino)-β-D-xylo-hexopyranose (1206717-74-9)

Guidance literature:

With ammonium iodide; tetra-(n-butyl)ammonium iodide; In toluene; for 1.5h; Reflux;

DOI:10.1002/ejoc.200900762

upstream raw materials:

1,6-anhydro-2,3,4-trideoxy-2,3-(tosylepimino)-β-D-ribo-hexopyranose

p-toluenesulfonyl chloride