4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid

Base Information

• Chemical Name: 4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid
• CAS No.: 1359740-23-0
• Molecular Formula: C₂₇H₂₆O₉
• Molecular Weight: 494.498
• Mol file: 1359740-23-0.mol

Synonyms:4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid

Chemical Property of 4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid

There total 1 articles about 4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

Ethyl 4-hydroxybenzoate (120-47-8) + 2-ethyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate) (6962-93-2) → 4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid (1359740-23-0)

Guidance literature:

Ethyl 4-hydroxybenzoate; 2-ethyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate); With potassium carbonate; In N,N-dimethyl-formamide; for 16h; Reflux;

With potassium hydroxide; In water; acetone; for 12h; Reflux;

With hydrogenchloride; In water; acetone; pH=2;

DOI:10.1021/ic202577z

Reference yield: 63.0%

uranyl nirate hexahydrate + 4,4'-[[2-[(4-carboxyphenoxy)methyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoic acid (1359740-23-0) → uranyl(4,4'-[[2-[(4-carboxyphenoxymethyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoate) (1359740-18-3)

Guidance literature:

In water; High Pressure; heating a mixt. of uranyl salt and ligand in aq. soln. at 180°C for 3 d, cooling to room temp.; elem. anal.; energy dispersive X-ray anal.;

DOI:10.1021/ic202577z

upstream raw materials:

Ethyl 4-hydroxybenzoate

2-ethyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate)

Downstream raw materials:

uranyl(4,4'-[[2-[(4-carboxyphenoxymethyl]-2-ethylpropane-1,3-diyl]dioxy]dibenzoate)