2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Base Information

Chemical Name:2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate
CAS No.:138785-40-7
Molecular Formula:C₄₇H₈₈INO₁₃SSi₄
Molecular Weight:1146.53
Hs Code.:

2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Synonyms:2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Suppliers and Price of 2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

There total 45 articles about 2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 134262-75-2
2-(trimethylsilyl)ethyl <(2,4,6-trideoxy-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-thio-β-D-ribo-hexopyranosyl)oxy>carbamate

: 138785-39-4
4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzoic acid chloride

: 138785-40-7
2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Guidance literature:: With dmap; triethylamine; In dichloromethane;
DOI:10.1021/jo951560x

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 138785-40-7
2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / CH₂Cl₂

2: Ph₃P-HBr / CH₂Cl₂

3: EtSH, K₂CO₃ / methanol

4: 85 percent / Et₃N, DMAP / CH₂Cl₂

With pyridine; dmap; triphenylphosphine hydrobromide; potassium carbonate; triethylamine; ethanethiol; In methanol; dichloromethane;
DOI:10.1021/jo951560x

Reference yield:

: 168567-07-5
4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylbenzaldehyde

: 138785-40-7
2,4,6-trideoxy-1-O-<<2-(trimethylsilyl)ethyl>amino>-3-O-<(1,1-dimethylethyl)dimethylsilyl>-4-β-D-ribo-hexopyranosyl 4-<(6-deoxy-2,4-O,O-bis<(1,1-dimethylethyl)dimethylsilyl>-3-O-methyl-α-L-mannopyranosyl)oxy>-5-iodo-2,3-dimethoxy-6-methylthiobenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaClO₂, NaHPO₄, 2.) (COCl₂)2 / 1.) H₂O, t-BuOH

2: 85 percent / Et₃N, DMAP / CH₂Cl₂

With dmap; sodium chlorite; (COCl₂)2; camphor-10-sulfonic acid; triethylamine; In dichloromethane;
DOI:10.1021/jo951560x