3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

Base Information

Chemical Name:3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene
CAS No.:474247-24-0
Molecular Formula:C₂₃H₂₆O₅
Molecular Weight:382.456
Hs Code.:

Synonyms:3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

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Technology Process of 3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

There total 4 articles about 3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 60695-85-4
2-Carbomethoxy-6-methoxy-benzoyl chloride

: 238752-40-4
2-Ethyl-1,2,3,4-tetrahydro-7-methoxynaphthalene

: 474247-24-0
3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

Guidance literature:: With aluminium trichloride; In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/S0040-4020(02)00740-8

Reference yield:

: 6836-19-7
7-Methoxy-1-tetralone

: 474247-24-0
3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

Guidance literature:: Multi-step reaction with 4 steps

1.1: BF₃*Et₂O / 2 h / 20 °C

1.2: 65 percent / sodium acetate / methanol / 4 h / Heating

2.1: 60 percent / HCl; hydrogen / 10 percent Pd/C / H₂O; methanol / 8 h / 2585.74 Torr

3.1: 77 percent / zinc; mercuric chloride; HCl / toluene; H₂O / 12 h / Heating

4.1: 70 percent / aluminium chloride / CH₂Cl₂ / 0 - 20 °C

With hydrogenchloride; aluminium trichloride; boron trifluoride diethyl etherate; hydrogen; mercury dichloride; zinc; palladium on activated charcoal; In methanol; dichloromethane; water; toluene; 3.1: Clemensen's reduction / 4.1: Friedel-Crafts acylation;
DOI:10.1016/S0040-4020(02)00740-8

Reference yield:

: 238752-38-0
2-acetyl-7-methoxy-3,4-dihydronaphthalen-1(2H)-one

: 474247-24-0
3-ethyl-6-methoxy-7-(2'-carbomethoxy-6'-methoxybenzoyl)-1,2,3,4-tetrahydronaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / HCl; hydrogen / 10 percent Pd/C / H₂O; methanol / 8 h / 2585.74 Torr

2: 77 percent / zinc; mercuric chloride; HCl / toluene; H₂O / 12 h / Heating

3: 70 percent / aluminium chloride / CH₂Cl₂ / 0 - 20 °C

With hydrogenchloride; aluminium trichloride; hydrogen; mercury dichloride; zinc; palladium on activated charcoal; In methanol; dichloromethane; water; toluene; 2: Clemensen's reduction / 3: Friedel-Crafts acylation;
DOI:10.1016/S0040-4020(02)00740-8