trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

Base Information

• Chemical Name: trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene
• CAS No.: 189135-07-7
• Molecular Formula: C₂₄H₁₉NO₂
• Molecular Weight: 353.42
• Mol file: 189135-07-7.mol

Synonyms:trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

Chemical Property of trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

There total 3 articles about trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-10b,10c-dimethyl-10b,10c-dihydropyrene (956-84-3) + 2-nitro-aniline (88-74-4) → trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene (189135-07-7) + trans-2,7-bis(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

Guidance literature:

With sulfuric acid; sodium nitrite; Yield given. Multistep reaction. Yields of byproduct given; 1.) H₂O, 0 deg C, 10 min, 2.) glacial AcOH, room temperature, 10 min;

DOI:10.1021/jo962337i

Reference yield:

trans-10b,10c-dimethyl-10b,10c-dihydropyrene (956-84-3) + 2-nitro-aniline (88-74-4) → trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene (189135-07-7) + trans-2,7-bis(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene + trans-2,4,7-tris(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

Guidance literature:

With sulfuric acid; sodium nitrite; Yield given. Multistep reaction; 1.) H₂O, 0 deg C, 10 min, 2.) glacial AcOH, room temperature, 10 min;

DOI:10.1021/jo962337i

Reference yield:

2-Nitrophenyldiazonium (25910-37-6) + 2-nitro-aniline (88-74-4) → trans-2-(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene (189135-07-7) + trans-2,7-bis(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene + trans-2,4,7-tris(2-nitrophenyl)-10b,10c-dimethyl-10b,10c-dihydropyrene

Guidance literature:

In acetic acid; for 0.166667h; Product distribution; Ambient temperature; Gomberg-Bachmann reaction with arenediazonium salts in acidic media; steric factors, effect of conjugation and electronic nature of substituents in diazonium salts;

DOI:10.1021/jo962337i

upstream raw materials:

2-Nitrophenyldiazonium

2-nitro-aniline

trans-10b,10c-dimethyl-10b,10c-dihydropyrene