[manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate

Base Information

• Chemical Name: [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate
• CAS No.: 218600-74-9
• Molecular Formula: C₂₄H₂₀B*C₃₀H₅₆MnN₄O₂
• Molecular Weight: 878.972
• Mol file: 218600-74-9.mol

Synonyms:[manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate

Chemical Property of [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate

There total 3 articles about [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[manganese(II)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] complex (218600-78-3) + sodium tetraphenyl borate (143-66-8) → [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate (218600-74-9)

Guidance literature:

In methanol; addn. of aerated soln. of NaBPh4, stirring for 1 h at room temp in air-atmosphere;

DOI:10.1002/(SICI)1521-3773(19981116)37:21<3005::AID-ANIE3005>3.0.CO;2-2

Reference yield:

5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (10368-90-8,10368-91-9,53187-81-8,54622-44-5,56144-66-2) → [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate (218600-74-9)

Guidance literature:

Multi-step reaction with 3 steps

1: acetonitrile

2: base / methanol

3: methanol

With base; In methanol; acetonitrile;

DOI:10.1002/(SICI)1521-3773(19981116)37:21<3005::AID-ANIE3005>3.0.CO;2-2

Reference yield:

3,5-Di-tert-butylcatechol (1020-31-1,122983-47-5,881376-69-8) + [manganese(II)((.+-.)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)Cl] (133962-75-1,99825-95-3) → [manganese(III)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] tetraphenylborate (218600-74-9)

Guidance literature:

Multi-step reaction with 2 steps

1: base / methanol

2: methanol

With base; In methanol;

DOI:10.1002/(SICI)1521-3773(19981116)37:21<3005::AID-ANIE3005>3.0.CO;2-2

upstream raw materials:

[manganese(II)((+/-)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)(3,5-di-tert-butylcatecholate)] complex

sodium tetraphenyl borate

3,5-Di-tert-butylcatechol

[manganese(II)((.+-.)l-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)Cl]