N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine

Base Information

Chemical Name:N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine
CAS No.:368-83-2
Molecular Formula:C8H6 F3 N O
Molecular Weight:189.137
Hs Code.:2928000090
DSSTox Substance ID:DTXSID10380502
Mol file:368-83-2.mol

Synonyms:N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine;368-83-2;N-{[3-(trifluoromethyl)phenyl]methylidene}hydroxylamine;3-(trifluoromethyl)benzaldehyde oxime;Benzaldehyde, 3-(trifluoromethyl)-, oxime;Maybridge1_008626;DTXSID10380502;3-(trifluoromethyl)benzaldehydeoxime;AKOS017263866;FT-0613920

Suppliers and Price of N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-(Trifluoromethyl)benzaldoxime
250mg
$ 45.00

SynQuest Laboratories
3-(Trifluoromethyl)benzaldoxime 97%
1 g
$ 93.00

SynQuest Laboratories
3-(Trifluoromethyl)benzaldoxime 97%
5 g
$ 228.00

Matrix Scientific
3-(Trifluoromethyl)benzaldoxime 97%
1g
$ 249.00

Apolloscientific
3-(Trifluoromethyl)benzaldoxime 97%
5g
$ 142.00

Apolloscientific
3-(Trifluoromethyl)benzaldoxime 97%
1g
$ 58.00

American Custom Chemicals Corporation
3-(TRIFLUOROMETHYL)BENZALDOXIME 95.00%
5G
$ 903.56

American Custom Chemicals Corporation
3-(TRIFLUOROMETHYL)BENZALDOXIME 95.00%
1G
$ 647.36

AK Scientific
3-(Trifluoromethyl)benzaldoxime
1g
$ 386.00

AHH
3-(Trifluoromethyl)benzaldoxime 97%
5g
$ 840.00

Total 19 raw suppliers

Chemical Property of N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine

Chemical Property:

Vapor Pressure:0.0975mmHg at 25°C
Melting Point:83-86°C
Refractive Index:1.461
Boiling Point:213.3°Cat760mmHg
PKA:10.46±0.10(Predicted)
Flash Point:82.8°C
PSA：32.59000
Density:1.27g/cm³
LogP:2.51350
XLogP3:2.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:1
Exact Mass:189.04014830
Heavy Atom Count:13
Complexity:190

Purity/Quality:

99%, ^*data from raw suppliers

3-(Trifluoromethyl)benzaldoxime ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 20/21/22-36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC(=C1)C(F)(F)F)C=NO

Technology Process of N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine

There total 3 articles about N-[[3-(trifluoromethyl)phenyl]methylidene]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 368-83-2
3-(trifluoromethyl)benzaldehyde oxime

Guidance literature:

Reference yield: 93.3%

: 454-89-7
3-Trifluoromethylbenzaldehyde

: 368-83-2
3-(trifluoromethyl)benzaldehyde oxime

Guidance literature:: With hydroxylamine hydrochloride; sodium acetate; In ethanol; at 45 ℃; for 1h;

Reference yield:

: 349-75-7
3-(trifluoromethyl)benzyl alcohol

: 368-83-2
3-(trifluoromethyl)benzaldehyde oxime

Guidance literature:: Multi-step reaction with 2 steps

1: potassium carbonate; fluorosulfonyl fluoride; dimethyl sulfoxide / 12 h / 20 °C

2: hydroxylamine hydrochloride; potassium carbonate / 20 °C

With fluorosulfonyl fluoride; hydroxylamine hydrochloride; potassium carbonate; dimethyl sulfoxide;
DOI:10.1002/ejoc.201900478