(3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

Base Information

Chemical Name:(3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine
CAS No.:1163143-58-5
Molecular Formula:C₂₅H₃₃NO₄SSi
Molecular Weight:471.693
Hs Code.:

Synonyms:(3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

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Technology Process of (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

There total 1 articles about (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4551-15-9
phenylthiotrimethylsilane

: C₂₀H₃₁NO₅Si

: 1163143-58-5
(3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; for 3h; Inert atmosphere;
DOI:10.1002/anie.200805724

Reference yield: 75.0%

: 1163143-58-5
(3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

: 1163143-60-9
(1S,5S,6S,8S)-2-benzyl-8-hydroxymethyl-6-phenylthio-3,7-dioxa-2-azabicyclo[3.3.1]-nonan-9-one

Guidance literature:: (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine; With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -30 - 20 ℃; for 16h; Inert atmosphere;

With water; In dichloromethane;
DOI:10.1002/anie.200805724

Reference yield: 63.0%

: 1163143-58-5
(3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine

: 69739-34-0
t-butyldimethylsiyl triflate

: 1163143-61-0
(1S,5S,6S,8S)-2-benzyl-8-(tert-butyldimethylsiloxymethyl)-6-phenylsulfanyl-3,7-dioxa-2-azabicyclo[3.3.1]nonan-9-one

Guidance literature:: (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine; t-butyldimethylsiyl triflate; In dichloromethane; at -30 - 20 ℃; for 16h; Inert atmosphere;

With triethylamine; In dichloromethane; at 0 ℃; Inert atmosphere;

With water; ammonium chloride; In dichloromethane;
DOI:10.1002/anie.200805724