(3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

Base Information

Chemical Name:(3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole
CAS No.:184873-90-3
Molecular Formula:C₁₈H₂₄O₄
Molecular Weight:304.386
Hs Code.:

Synonyms:(3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

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Chemical Property of (3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

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Technology Process of (3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

There total 5 articles about (3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 184873-89-0
((3aR,6S,6aR)-2,2-Dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl)-acetic acid methyl ester

: 184873-90-3
(3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminum hydride / CH₂Cl₂; toluene / 2 h / -40 °C

2: 1.) NaH, 2.) tetrabutylammonium bromide / 1.) THF, RT, 20 min, 2.) THF, RT, overnight

With tetrabutylammomium bromide; sodium hydride; diisobutylaluminium hydride; In dichloromethane; toluene;
DOI:10.1021/jm960525v

Reference yield:

: ((3aR,6aR)-2,2-Dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl)-acetic acid ethyl ester

: 184873-90-3
(3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / tetrahydrofuran / 0.5 h / -10 °C

2: 1.) NaH, 2.) tetrabutylammonium bromide / 1.) THF, RT, 20 min, 2.) THF, RT, overnight

With lithium aluminium tetrahydride; tetrabutylammomium bromide; sodium hydride; In tetrahydrofuran;
DOI:10.1021/jm960525v

Reference yield:

: 2-[(3aR,6aR)-2,2-Dimethyl-dihydro-furo[2,3-d][1,3]dioxol-(6E)-ylidene]-ethanol

: 184873-90-3
(3aR,6S,6aR)-6-(2-Benzyloxy-ethyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxole

Guidance literature:: Multi-step reaction with 3 steps

1: 64 percent / propionic acid / 16 h / 135 °C

2: LiAlH₄ / tetrahydrofuran / 0.5 h / -10 °C

3: 1.) NaH, 2.) tetrabutylammonium bromide / 1.) THF, RT, 20 min, 2.) THF, RT, overnight

With lithium aluminium tetrahydride; tetrabutylammomium bromide; sodium hydride; propionic acid; In tetrahydrofuran;
DOI:10.1021/jm960525v