3-(methoxycarbonyl)-5--1,3-cyclohexadiene

Base Information

Chemical Name:3-(methoxycarbonyl)-5--1,3-cyclohexadiene
CAS No.:106094-00-2
Molecular Formula:C₁₃H₁₆O₇
Molecular Weight:284.266
Hs Code.:

3-(methoxycarbonyl)-5-<bis(methoxycarbonyl)methoxy>-1,3-cyclohexadiene

Synonyms:3-(methoxycarbonyl)-5--1,3-cyclohexadiene

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Chemical Property of 3-(methoxycarbonyl)-5--1,3-cyclohexadiene

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Technology Process of 3-(methoxycarbonyl)-5--1,3-cyclohexadiene

There total 4 articles about 3-(methoxycarbonyl)-5--1,3-cyclohexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 6773-29-1
dimethyl diazomalonate

: 71143-26-5
methyl 1-hydroxy-cyclohexa-2,4-diene-3-carboxylate

: 106094-00-2
3-(methoxycarbonyl)-5--1,3-cyclohexadiene

Guidance literature:: With rhodium(II) acetate; In benzene; for 0.583333h; Heating;
DOI:10.1021/ja00238a029

Reference yield:

: endo-8-bromo-6-oxabicyclo<3.2.1>octa-2-en-7-one

: 106094-00-2
3-(methoxycarbonyl)-5--1,3-cyclohexadiene

Guidance literature:: Multi-step reaction with 3 steps

1: NaOH / tetrahydrofuran / 15 h / Ambient temperature

2: H₂O; hexamethylphosphoric acid triamide / 32 h / Ambient temperature

3: 53 percent / rhodium acetate / benzene / 0.58 h / Heating

With rhodium(II) acetate; sodium hydroxide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; water; benzene;
DOI:10.1021/ja00238a029

Reference yield:

: Sodium; 3-hydroxy-cyclohexa-1,5-dienecarboxylate

: 106094-00-2
3-(methoxycarbonyl)-5--1,3-cyclohexadiene

Guidance literature:: Multi-step reaction with 2 steps

1: H₂O; hexamethylphosphoric acid triamide / 32 h / Ambient temperature

2: 53 percent / rhodium acetate / benzene / 0.58 h / Heating

With rhodium(II) acetate; In N,N,N,N,N,N-hexamethylphosphoric triamide; water; benzene;
DOI:10.1021/ja00238a029