(Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

Base Information

Chemical Name:(Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide
CAS No.:1384985-10-7
Molecular Formula:C₁₇H₂₇O₄PSi
Molecular Weight:354.458
Hs Code.:

Synonyms:(Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

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Chemical Property of (Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

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Technology Process of (Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

There total 1 articles about (Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 4090-55-5
2-chloro-5,5-dimethyl[1,3,2]dioxaphosphinane 2-oxide

: (+/-)-(Z)-1-(dimethylphenylsilyl)-1-buten-3-ol

: 1384985-10-7
(Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

Guidance literature:: (+/-)-(Z)-1-(dimethylphenylsilyl)-1-buten-3-ol; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; In tetrahydrofuran; at -78 ℃; for 0.75h; Inert atmosphere;

2-chloro-5,5-dimethyl[1,3,2]dioxaphosphinane 2-oxide; In tetrahydrofuran; at -78 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1055/s-0031-1290818

Reference yield:

: 121213-49-8
9-((CH₂)3(C₆H₄)(OMe)2)-9-borabicyclo{3.3.1}nonane

: 1384985-10-7
(Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

: 1384985-18-5
(E)-[7-(3,4-dimethoxyphenyl)hept-2-en-4-yl]dimethyl(phenyl)silane

Guidance literature:: With potassium tert-butylate; copper (I) acetate; In tetrahydrofuran; at 60 ℃; for 6h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1055/s-0031-1290818

Reference yield:

: 1384985-10-7
(Z)-2-{[4-(dimethylphenylsilyl)but-3-en-2-yl]oxy}-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide

: C₁₈H₂₇BO₂S

: (E)-5-(dimethylphenylsilyl)-1-(thiophen-2-yl)oct-6-en-1-yl acetate

Guidance literature:: With potassium tert-butylate; copper (I) acetate; In tetrahydrofuran; at 60 ℃; for 6h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1055/s-0031-1290818